Insight into the catalytic activity for a series of synthesized and newly designed phosphonium-based ionic liquids on the fixation of carbon dioxide
文献类型：期刊论文
| 作者 | Wang, Li1; Li, Ping1; Li, Ya1; He, Hongqing2 ; Zhang, Jinglai1
|
| 刊名 | THEORETICAL CHEMISTRY ACCOUNTS
 |
| 出版日期 | 2015-05-20 |
| 卷号 | 134期号:6 |
| 关键词 | Functionalized phosphonium-based ionic liquids CO2 Chain length Cation |
| 英文摘要 | Various catalysts have been explored for the coupling reaction of carbon dioxide with propylene oxide in the past decade. However, the search for high-efficiency single-component catalyst in the absence of metal and solvent is still a challenging issue. In this work, the catalytic activity of a series of functionalized phosphonium-based ionic liquids (FPBILs) is investigated by density functional theory. The influences of functional group, chain length of cation, and anion on the catalytic performance have been explored. The carboxyl-functionalized FPBIL with the moderate alkyl chain length presents the best catalytic activity among all investigated catalysts. On the basis of above information, a new sulfonyl hydroxide-functionalized FPBIL is designed. Moreover, its catalytic activity is theoretically examined as compared with that of carboxyl-functionalized FPBIL. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | COUPLING REACTION ; PROPYLENE-OXIDE ; CO2 INSERTION ; EPOXIDES ; CYCLOADDITION ; MECHANISM ; THERMOCHEMISTRY ; EXCHANGE ; AL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355942500001 |
| 公开日期 | 2015-07-28 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4751]  |
| 专题 | 武汉物理与数学研究所_理论与交叉研究部 |
| 作者单位 | 1.Henan Univ, Coll Chem & Chem Engn, Inst Environm & Analyt Sci, Kaifeng 475004, Henan, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Li,Li, Ping,Li, Ya,et al. Insight into the catalytic activity for a series of synthesized and newly designed phosphonium-based ionic liquids on the fixation of carbon dioxide[J]. THEORETICAL CHEMISTRY ACCOUNTS,2015,134(6). |
| APA | Wang, Li,Li, Ping,Li, Ya,He, Hongqing,&Zhang, Jinglai.(2015).Insight into the catalytic activity for a series of synthesized and newly designed phosphonium-based ionic liquids on the fixation of carbon dioxide.THEORETICAL CHEMISTRY ACCOUNTS,134(6). |
| MLA | Wang, Li,et al."Insight into the catalytic activity for a series of synthesized and newly designed phosphonium-based ionic liquids on the fixation of carbon dioxide".THEORETICAL CHEMISTRY ACCOUNTS 134.6(2015). |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。