中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
An ionophore-Nafion modified bismuth electrode for the analysis of cadmium(II)

文献类型:期刊论文

作者Jiang, Lin1,2,3; Wang, Yuane1,2,3; Ding, Jiawang1,3; Lou, Tingting1,2,3; Qin, Wei1,4
刊名ELECTROCHEMISTRY COMMUNICATIONS
出版日期2010-02-01
卷号12期号:2页码:202-205
关键词Ionophore Nafion Bismuth electrode Cadmium Stripping voltammetry
英文摘要A novel ionophore-Nafion modified bismuth electrode is described for sensitive and selective anodic stripping analysis of cadmium(II). The electrode is prepared by coating the glassy carbon electrode with the cadmium ionophore N,N,N',N'-tetrabutyl-3,6-dioxaoctanedi(thioamide) and Nafion composite. Bismuth is deposited in situ on the electrode surface by plating simultaneously with cadmium in sample solution. Numerous key variables affecting the current response of cadmium have been optimized. The electrode has a linear concentration range of 0.5-10 nM with a deposition time of 180 s. The detection limit is 1.3 x 10(-10) M and the relative standard deviations for 0.5 and 7 nM cadmium are 6.5% and 4.5%, respectively. The proposed electrode shows excellent selectivity over other heavy metals, such as copper, lead and indium. The attractive performance of such electrode offers a feasible way to monitor trace cadmium(II) rapidly and precisely in complex matrixes. (C) 2009 Elsevier B.V. All rights reserved.
收录类别SCI
语种英语
WOS记录号WOS:000274878400007
源URL[http://ir.qdio.ac.cn/handle/337002/32763]  
专题海洋研究所_海洋生态与环境科学重点实验室
作者单位1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
4.Yantai Univ, Sch Oceanol, Yantai 264005, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Lin,Wang, Yuane,Ding, Jiawang,et al. An ionophore-Nafion modified bismuth electrode for the analysis of cadmium(II)[J]. ELECTROCHEMISTRY COMMUNICATIONS,2010,12(2):202-205.
APA Jiang, Lin,Wang, Yuane,Ding, Jiawang,Lou, Tingting,&Qin, Wei.(2010).An ionophore-Nafion modified bismuth electrode for the analysis of cadmium(II).ELECTROCHEMISTRY COMMUNICATIONS,12(2),202-205.
MLA Jiang, Lin,et al."An ionophore-Nafion modified bismuth electrode for the analysis of cadmium(II)".ELECTROCHEMISTRY COMMUNICATIONS 12.2(2010):202-205.

入库方式: OAI收割

来源:海洋研究所

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