中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
On-Site Visual Detection of Hydrogen Sulfide in Air Based on Enhancing the Stability of Gold Nanoparticles

文献类型:期刊论文

作者Zhang, Zhiyang1,2,3; Chen, Zhaopeng1,2; Wang, Shasha1,2,3; Qu, Chengli1,2; Chen, Lingxin1,2
刊名ACS APPLIED MATERIALS & INTERFACES
出版日期2014-05-14
卷号6期号:9页码:6300-6307
关键词hydrogen sulfide visual detection gold nanoparticles stability
ISSN号1944-8244
产权排序[Zhang, Zhiyang; Chen, Zhaopeng; Wang, Shasha; Qu, Chengli; Chen, Lingxin] Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China; [Zhang, Zhiyang; Chen, Zhaopeng; Wang, Shasha; Qu, Chengli; Chen, Lingxin] YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China; [Zhang, Zhiyang; Wang, Shasha] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
通讯作者Chen, ZP (reprint author), Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China. zhpchen@yic.ac.cn ; lxchen@yic.ac.cn
中文摘要We have described a simple and low-cost visual method for on-site detection of hydrogen sulfide (H2S) in air based on the antiaggregation of gold nanoparticles (AuNPs). The bubbling of H2S into a weak alkaline buffer solution leads to the formation of HS-, which can stabilize the AuNPs and ensure the AuNPs maintain their red color even in a Tris buffer solution containing 80 mM NaCl with the presence of Tween 80. The stabilization of the AuNPs is attributed to the adsorption of negatively charged S2- on the AuNPs surface. In contrast, without the bubbling of H2S, AuNPs aggregate and change color from red to blue. Under optimal conditions, the proposed method exhibits excellent visual sensitivity with a naked-eye detectable limit of 0.5 ppm (v/v), making the on-site detection of H2S possible. This method also possesses good selectivity toward H2S over other gases by using a simple SO2 removal device. The successful determination of the concentrations of H2S in local
英文摘要We have described a simple and low-cost visual method for on-site detection of hydrogen sulfide (H2S) in air based on the antiaggregation of gold nanoparticles (AuNPs). The bubbling of H2S into a weak alkaline buffer solution leads to the formation of HS-, which can stabilize the AuNPs and ensure the AuNPs maintain their red color even in a Tris buffer solution containing 80 mM NaCl with the presence of Tween 80. The stabilization of the AuNPs is attributed to the adsorption of negatively charged S2- on the AuNPs surface. In contrast, without the bubbling of H2S, AuNPs aggregate and change color from red to blue. Under optimal conditions, the proposed method exhibits excellent visual sensitivity with a naked-eye detectable limit of 0.5 ppm (v/v), making the on-site detection of H2S possible. This method also possesses good selectivity toward H2S over other gases by using a simple SO2 removal device. The successful determination of the concentrations of H2S in local
学科主题Nanoscience & Nanotechnology; Materials Science, Multidisciplinary
研究领域[WOS]Science & Technology - Other Topics ; Materials Science
关键词[WOS]COLORIMETRIC DETECTION ; ELECTROCHEMICAL SENSORS ; OPTICAL-PROPERTIES ; FLUORESCENT-PROBE ; LIVING CELLS ; SULFUR ; DNA ; RAMAN ; GAS ; MOLECULES
收录类别SCI
语种英语
WOS记录号WOS:000336075300037
源URL[http://ir.yic.ac.cn/handle/133337/8745]  
专题烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
烟台海岸带研究所_山东省海岸带环境工程技术研究中心
作者单位1.Chinese Acad Sci, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai Inst Coastal Zone Res YIC, Yantai 264003, Shandong, Peoples R China
2.YICCAS, Shandong Prov Key Lab Coastal Environm Proc, Yantai 264003, Shandong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Zhiyang,Chen, Zhaopeng,Wang, Shasha,et al. On-Site Visual Detection of Hydrogen Sulfide in Air Based on Enhancing the Stability of Gold Nanoparticles[J]. ACS APPLIED MATERIALS & INTERFACES,2014,6(9):6300-6307.
APA Zhang, Zhiyang,Chen, Zhaopeng,Wang, Shasha,Qu, Chengli,&Chen, Lingxin.(2014).On-Site Visual Detection of Hydrogen Sulfide in Air Based on Enhancing the Stability of Gold Nanoparticles.ACS APPLIED MATERIALS & INTERFACES,6(9),6300-6307.
MLA Zhang, Zhiyang,et al."On-Site Visual Detection of Hydrogen Sulfide in Air Based on Enhancing the Stability of Gold Nanoparticles".ACS APPLIED MATERIALS & INTERFACES 6.9(2014):6300-6307.

入库方式: OAI收割

来源:烟台海岸带研究所

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