中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Crystal Morphologies of Organolead Trihalide in Mesoscopic/Planar Perovskite Solar Cells

文献类型:期刊论文

作者Zhou, Yuanyuan1; Vasiliev, Alexander L.1; Wu, Wenwen1; Yang, Mengjin2; Pang, Shuping3; Zhu, Kai2; Padture, Nitin P.1
刊名JOURNAL OF PHYSICAL CHEMISTRY LETTERS
出版日期2015-06-18
卷号6期号:12页码:2292-2297
英文摘要

The crystal morphology of organolead trihalide perovskite (OTP) light absorbers can have profound influence on the perovskite solar cells (PSCs) performance. Here we have used a combination of conventional transmission electron microscopy (TEM) and high-resolution TEM (HRTEM), in cross-section and plan-view, to characterize the morphologies of a solution-processed OTP (CH3NH3PbI3 or MAPbI(3)) within mesoporous TiO2 scaffolds and within capping and planar layers. Studies of TEM specimens prepared with and without the use of focused ion beam (FIB) show that FIBing is a viable method for preparing TEM specimens. HRTEM studies, in conjunction with quantitative X-ray diffraction, show that MAPbI(3) perovskite within mesoporous TiO2 scaffold has equiaxed grains of size 10-20 nm and relatively low crystallinity. In contrast, the grain size of MAPbI(3) perovskite in the capping and the planar layers can be larger than 100 nm in our PSCs, and the grains can be elongated and textured, with relatively high crystallinity. The observed differences in the performance of planar and mesoscopic-planar hybrid PSCs can be attributed in part to the striking differences in their perovskite-grain morphologies.

WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
关键词[WOS]HIGH-PERFORMANCE ; DEVICE PERFORMANCE ; THIN-FILMS ; CRYSTALLIZATION ; HYSTERESIS ; EMERGENCE ; LIGHT ; LAYER
收录类别SCI
语种英语
WOS记录号WOS:000356758100024
源URL[http://ir.qibebt.ac.cn/handle/337004/3988]  
专题青岛生物能源与过程研究所_仿生能源与储能系统团队
作者单位1.Brown Univ, Sch Engn, Providence, RI 02912 USA
2.Natl Renewable Energy Lab, Chem & Mat Sci Ctr, Golden, CO 80401 USA
3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Yuanyuan,Vasiliev, Alexander L.,Wu, Wenwen,et al. Crystal Morphologies of Organolead Trihalide in Mesoscopic/Planar Perovskite Solar Cells[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2015,6(12):2292-2297.
APA Zhou, Yuanyuan.,Vasiliev, Alexander L..,Wu, Wenwen.,Yang, Mengjin.,Pang, Shuping.,...&Padture, Nitin P..(2015).Crystal Morphologies of Organolead Trihalide in Mesoscopic/Planar Perovskite Solar Cells.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,6(12),2292-2297.
MLA Zhou, Yuanyuan,et al."Crystal Morphologies of Organolead Trihalide in Mesoscopic/Planar Perovskite Solar Cells".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 6.12(2015):2292-2297.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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