LEACHING POTENTIAL OF NONSTEROIDAL ANTI-INFLAMMATORY DRUGS IN SOILS
文献类型:期刊论文
作者 | Xu, Jian ; Wu, Laosheng ; Chen, Weiping ; Chang, Andrew C. |
刊名 | ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
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出版日期 | 2010-04 |
卷号 | 29期号:4页码:800-807 |
关键词 | Nonsteroidal anti-inflammatory drugs Leaching Soil Groundwater contamination |
中文摘要 | Nonsteroidal anti-inflammatory drugs (NSAIDs) in soils resulting from application of municipal wastewater or biosolids may migrate through soils intact or be transformed and reach groundwater. In the present study, the leaching potential of four NSAIDs (ibuprofen, naproxen, ketoprofen, and diclofenac sodium) in three U.S. cropland soils was evaluated, and the effect of CaCl2 solution (as an index of salinity), dissolved organic matter (DOM), and polyacrylamide (PAM) amendment was investigated. The soils were spiked with selected NSAIDs, incubated for 24h followed by 7-d storage in glass flasks, and then packed into stainless steel columns and leached with deionized water (DIW), 10 mM CaCl2, DOM (DOC 34 mg/L), and PAM solution (1.0 mg/L) by gravity. Initial concentrations of ibuprofen, naproxen; ketoprofen, and diclofenac sodium in the three packed soils were 1.93 to 2.07. 1.74 to 2.27, 1.79 to 2.16, and 1.99 to 2.13 mg/kg, respectively. Maximum concentrations of the above NSAIDs in column effluents were 1.23, 0.92, 0.69, and 1.12 mg/L. respectively, when the soil was leached with 10 pore volumes of water, which occupied 17.4, 11.1, 9.6, and 15.2% of the total chemicals in each soil column. Dissolved organic matter or PAM solution did not facilitate the NSAIDs release from soils. The CaCl2 solution, however, reduced the amounts of NSAIDs leached from all three soils. Leaching of NSAIDs differed among the three tested soils. The results suggest that the leaching of NSAIDs through soil to water is significant, and the mobility of NSAIDs in soil is related to their chemicals' characteristics (such as pK(a) values) and soil properties (such as soil organic matter and clay content). Amending soil with DOM or PAM does not significantly affect the leaching behavior of NSAIDs in soil, whereas increasing the salinity of the irrigation water may decrease the extent of contamination of groundwater posed by NSAIDs. Environ. Toxicol. Chem. 2010;29:800-807. (C) 2009 SETAC |
WOS记录号 | WOS:000276604100006 |
源URL | [http://ir.rcees.ac.cn/handle/311016/20992] ![]() |
专题 | 生态环境研究中心_城市与区域生态国家重点实验室 |
推荐引用方式 GB/T 7714 | Xu, Jian,Wu, Laosheng,Chen, Weiping,et al. LEACHING POTENTIAL OF NONSTEROIDAL ANTI-INFLAMMATORY DRUGS IN SOILS[J]. ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY,2010,29(4):800-807. |
APA | Xu, Jian,Wu, Laosheng,Chen, Weiping,&Chang, Andrew C..(2010).LEACHING POTENTIAL OF NONSTEROIDAL ANTI-INFLAMMATORY DRUGS IN SOILS.ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY,29(4),800-807. |
MLA | Xu, Jian,et al."LEACHING POTENTIAL OF NONSTEROIDAL ANTI-INFLAMMATORY DRUGS IN SOILS".ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY 29.4(2010):800-807. |
入库方式: OAI收割
来源:生态环境研究中心
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