中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Speciation of methylmercury in rice grown from a mercury mining area

文献类型:期刊论文

作者Li, Lu ; Wang, Feiyue ; Meng, Bo ; Lemes, Marcos ; Feng, Xinbin ; Jiang, Guibin
刊名ENVIRONMENTAL POLLUTION
出版日期2010-10
卷号158期号:10页码:3103-3107
关键词Rice Mercury Methylmercury Speciation Risk assessment Enzymatic hydrolysis ICP-MS LC
中文摘要Monomethylmercury (CH(3)Hg(+) and its complexes; MeHg hereafter) is a known developmental neurotoxin. Recent studies have shown that rice (Oryza sativa L) grain grown from mercury (Hg) mining areas may contain elevated MeHg concentrations, raising concerns over the health of local residents who consume rice on a daily basis. An analytical method employing high performance liquid chromatography (HPLC) - inductively coupled plasma mass spectrometry (ICP-MS) following enzymatic hydrolysis was developed to analyze the speciation of MeHg in uncooked and cooked white rice grain grown from the vicinity of a Hg mine in China. The results revealed that the MeHg in the uncooked rice is present almost exclusively as CH(3)Hg-L-cysteinate (CH(3)HgCys), a complex that is thought to be responsible for the transfer of MeHg across the blood brain and placental barriers. Although cooking does not change the total Hg or total MeHg concentration in rice, no CH(3)HgCys is measurable after cooking, suggesting that most, if not all, of the CH(3)HgCys is converted to other forms of MeHg, the identity and toxicity of which remain elusive. (c) 2010 Elsevier Ltd. All rights reserved.
WOS记录号WOS:000282260200014
源URL[http://ir.rcees.ac.cn/handle/311016/21144]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
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GB/T 7714
Li, Lu,Wang, Feiyue,Meng, Bo,et al. Speciation of methylmercury in rice grown from a mercury mining area[J]. ENVIRONMENTAL POLLUTION,2010,158(10):3103-3107.
APA Li, Lu,Wang, Feiyue,Meng, Bo,Lemes, Marcos,Feng, Xinbin,&Jiang, Guibin.(2010).Speciation of methylmercury in rice grown from a mercury mining area.ENVIRONMENTAL POLLUTION,158(10),3103-3107.
MLA Li, Lu,et al."Speciation of methylmercury in rice grown from a mercury mining area".ENVIRONMENTAL POLLUTION 158.10(2010):3103-3107.

入库方式: OAI收割

来源:生态环境研究中心

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