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Characterization and application of chars produced from pinewood pyrolysis and hydrothermal treatment

文献类型:期刊论文

作者Liu, Zhengang ; Zhang, Fu-Shen ; Wu, Jianzhi
刊名FUEL
出版日期2010-02
卷号89期号:2页码:510-514
关键词Biomass Adsorption Oxygen-containing group Heavy metal Wastewater
中文摘要Two types of pinewood chars, hydrothermal char (H300) and pyrolytic char (P700) from biomass-toenergy conversion were characterized and used as adsorbent for the copper removal from aqueous solution. The result showed that the pinewood underwent a deeper carbonization during pyrolysis process and more activated sites available and stable carbon-oxygen complex existed after hydrothermal treatment. Comparing with raw pinewood, hydrothermal treatment increased 95% total oxygen-containing groups ( carboxylic, lactone and phenolic group) while 56% oxygen-containing groups decreased after pyrolysis process. SEM analysis indicated that both hydrothermal and pyrolytic processes developed rough surface with new cavities on the chars, and the BET surface area were 21 and 29 m(2)/g for H300 and P700, respectively. Although H300 had lower surface area, its adsorption capacity for copper was much higher than P700 since ion-exchange reaction was the predominant removal mechanism by H300, while physical adsorption dominated by P700. The adsorption data could be well described by Langmuir isotherm model for copper onto both H300 and P700. (C) 2009 Elsevier Ltd. All rights reserved.
WOS记录号WOS:000271295400031
源URL[http://ir.rcees.ac.cn/handle/311016/21180]  
专题生态环境研究中心_环境纳米材料实验室
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GB/T 7714
Liu, Zhengang,Zhang, Fu-Shen,Wu, Jianzhi. Characterization and application of chars produced from pinewood pyrolysis and hydrothermal treatment[J]. FUEL,2010,89(2):510-514.
APA Liu, Zhengang,Zhang, Fu-Shen,&Wu, Jianzhi.(2010).Characterization and application of chars produced from pinewood pyrolysis and hydrothermal treatment.FUEL,89(2),510-514.
MLA Liu, Zhengang,et al."Characterization and application of chars produced from pinewood pyrolysis and hydrothermal treatment".FUEL 89.2(2010):510-514.

入库方式: OAI收割

来源:生态环境研究中心

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