Macro-, micro-, nano- and crystal structures of a homodinuclear complex [NH3(CH2)(3)NH3](2){Na-2[(C6H4O2)(2)](C6H4O2H)(2)}
文献类型：期刊论文
| 作者 | Lu Xiao-Ming; Wei Chun-Xia; Wang Zhen; Ye Chao-Hui |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2007-08-01 |
| 卷号 | 25期号:8页码:1126-1130 |
| 关键词 | sodium complex 1 synthesis crystal structure 2-dihydroxybenzene |
| 英文摘要 | A homodinuclear complex (NH3CH2CH2CH2NH3)(2)[Na-2[(C6H4O2)(2)](C6H4O2H)(2)} (1) has been synthesized by a solution-based self-assembly route. It crystallized in monoclinic system with space group P2(1)/c. Every sodium ion coordinates in a tetragonal prism fashion with two 0 atoms of a terminal chelating catecholate ligand and three 0 atoms from two bridging catecholate ligands. Two neighboring NaO5 tetragonal prisms are edge-shared and centrosymmetric with regard to the inversion center to form a binuclear cluster (Na-2[(C6H4O2)(2)](C6H4OOH)(2)}(4-) anion. The complex anions were aligned parallelly by pi-pi interaction and linked with the protonated 1,3-propylenediamine through hydrogen bonds which were assembled into a multi-lamellar structure with channels. The crystal exhibits rectangular geometry with an interior triangle hollow structure under optical microscopy. And the scanning electron microscopy (SEM) indicates that the wall of the tubes shows multi-lamella morphologies. Further, the transmission electron microscopy (TEM) reveals that the crystal is composed of multi-lamellar nano-tubes with diameters less than 100 nm. The molecular structure of the complex was compared with that of its isomer complex 2. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | EPR-SPECTRA ; CIS-DIOXO-MOLYBDENUM(V) ; ENZYMES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000248877900015 |
| 公开日期 | 2015-08-18 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/4914]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu Xiao-Ming,Wei Chun-Xia,Wang Zhen,et al. Macro-, micro-, nano- and crystal structures of a homodinuclear complex [NH3(CH2)(3)NH3](2){Na-2[(C6H4O2)(2)](C6H4O2H)(2)}[J]. CHINESE JOURNAL OF CHEMISTRY,2007,25(8):1126-1130. |
| APA | Lu Xiao-Ming,Wei Chun-Xia,Wang Zhen,&Ye Chao-Hui.(2007).Macro-, micro-, nano- and crystal structures of a homodinuclear complex [NH3(CH2)(3)NH3](2){Na-2[(C6H4O2)(2)](C6H4O2H)(2)}.CHINESE JOURNAL OF CHEMISTRY,25(8),1126-1130. |
| MLA | Lu Xiao-Ming,et al."Macro-, micro-, nano- and crystal structures of a homodinuclear complex [NH3(CH2)(3)NH3](2){Na-2[(C6H4O2)(2)](C6H4O2H)(2)}".CHINESE JOURNAL OF CHEMISTRY 25.8(2007):1126-1130. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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