New eremophilane-type sesquiterpenes from Ligularia lapathifolia
文献类型:期刊论文
作者 | Li, YS; Wang, ZT; Zhang, M; Zhou, H; Chen, JJ![]() |
刊名 | PLANTA MEDICA
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出版日期 | 2004-03-01 |
卷号 | 70期号:3页码:239-243 |
关键词 | Ligularia lapathifolia Asteraceae eremophilane-type sesquiterpenes photooxygenation |
英文摘要 | Seven new eremophilanolides were isolated from the roots and rhizomes of Ligularia lapathifolia. Their structures were established as 3beta-angeloyloxy-8betaH-eremophil-7(11)-ene-12,8alpha(14beta,6alpha)-diolide, 3beta-angeloyloxy-8beta-hydroxyeremophil-7(11)-ene-12,8alpha(14beta,6alpha)-diolide,3beta-angeloyloxy-8beta-methoxyeremophil-7(11)-ene-12,8alpha(14beta,6alpha)-diolide,3beta-angeloyloxy-8beta -ethoxyeremophil-7(11)-ene-12,8alpha (14beta,6alpha)-diolide, 3beta-angeloyloxy-10beta-hydroxyeremophil-8(9),7(11)-diene-12,8(14beta,6alpha)-diolide, 3beta-angeloyloxy-8,12-expoy-12alpha-hydroxy-8beta-methoxyeremophil-7(11)-en-14beta,6alpha-olide and 3beta-angeloyloxyeremophilan-7,11-dien-14beta,6alpha-olide, by means of spectroscopic analyses. Moreover, application of a photooxygenation reaction on 7 resulted in the generation of 2 with an alpha,beta-unsaturated gamma-lactone moiety. This biomimetic transformation supports a biogenetic pathway proposed for 2. |
类目[WOS] | Plant Sciences ; Chemistry, Medicinal ; Pharmacology & Pharmacy |
研究领域[WOS] | Plant Sciences ; Pharmacology & Pharmacy |
关键词[WOS] | OXYGENATION ; FURANS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000220573600009 |
源URL | [http://ir.kib.ac.cn/handle/151853/23985] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China 2.China Pharmaceut Univ, Dept Pharmacognosy, Nanjing, Peoples R China 3.Chinese Acad Sci, Kunming Inst Bot, Kunming, Peoples R China |
推荐引用方式 GB/T 7714 | Li, YS,Wang, ZT,Zhang, M,et al. New eremophilane-type sesquiterpenes from Ligularia lapathifolia[J]. PLANTA MEDICA,2004,70(3):239-243. |
APA | Li, YS,Wang, ZT,Zhang, M,Zhou, H,Chen, JJ,&Lu, SD.(2004).New eremophilane-type sesquiterpenes from Ligularia lapathifolia.PLANTA MEDICA,70(3),239-243. |
MLA | Li, YS,et al."New eremophilane-type sesquiterpenes from Ligularia lapathifolia".PLANTA MEDICA 70.3(2004):239-243. |
入库方式: OAI收割
来源:昆明植物研究所
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