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Pretreatments of Co3O4 at moderate temperature for CO oxidation at-80 degrees C

文献类型:期刊论文

作者Yu, Yunbo; Takei, Takashi; Ohashi, Hironori; He, Hong; Zhang, Xiuli; Haruta, Masatake
刊名JOURNAL OF CATALYSIS
出版日期2009-10-25
卷号267期号:2页码:121-128
关键词CO oxidation Moisture Pretreatment Surface oxygen vacancy Tricobalt tetraoxide
中文摘要Heterogeneous catalysts that can work at ambient temperature are useful for in-door air quality control, pure gas production for fuel cells and semiconductors, gas sensing, and so forth. Deposition of gold nanoparticles on base metal oxide is known to provide highly active catalysts for CO oxidation at temperatures below room temperature. Here we report that some select base metal oxides such as Co3O4, MnO2, and NiO are intrinsically active catalysts for CO oxidation below 50 degrees C when pretreated at moderate temperature between 150 and 250 degrees C in a stream of non-reducing dry gases, for example, dry air, CO in air, or N-2. These metal oxides are p-type semiconductors and form surface excess oxygen adsorbed at oxygen vacancies which are created by the above pretreatments. (C) 2009 Elsevier Inc. All rights reserved.
WOS记录号WOS:000271112500005
源URL[http://ir.rcees.ac.cn/handle/311016/21441]  
专题生态环境研究中心_大气环境科学实验室
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GB/T 7714
Yu, Yunbo,Takei, Takashi,Ohashi, Hironori,et al. Pretreatments of Co3O4 at moderate temperature for CO oxidation at-80 degrees C[J]. JOURNAL OF CATALYSIS,2009,267(2):121-128.
APA Yu, Yunbo,Takei, Takashi,Ohashi, Hironori,He, Hong,Zhang, Xiuli,&Haruta, Masatake.(2009).Pretreatments of Co3O4 at moderate temperature for CO oxidation at-80 degrees C.JOURNAL OF CATALYSIS,267(2),121-128.
MLA Yu, Yunbo,et al."Pretreatments of Co3O4 at moderate temperature for CO oxidation at-80 degrees C".JOURNAL OF CATALYSIS 267.2(2009):121-128.

入库方式: OAI收割

来源:生态环境研究中心

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