Adsorption kinetics, isotherms and thermodynamics of atrazine on surface oxidized multiwalled carbon nanotubes
文献类型:期刊论文
作者 | Chen, Guang-Cai ; Shan, Xiao-Quan ; Zhou, Yi-Quan ; Shen, Xiu-e ; Huang, Hong-Lin ; Khan, Shahamat U. |
刊名 | JOURNAL OF HAZARDOUS MATERIALS
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出版日期 | 2009-09-30 |
卷号 | 169期号:1页码:912-918 |
关键词 | Adsorption Atrazine Carbon nanotubes Kinetics Thermodynamics |
中文摘要 | The adsorption kinetics, isotherms and thermodynamic of atrazine on multiwalled carbon nanotubes (MWCNTs) containing 0.85%, 2.16%, and 7.07% oxygen was studied. Kinetic analyses were performed using pseudo-first-order, pseudo-second-order and intraparticle diffusion models. The regression results showed that the pseudo-second-order law fit the adsorption kinetics. The calculated thermodynamic parameters indicated that adsorption of atrazine on MWCNTs was spontaneous and exothermic. Standard free energy (Delta G(0)) became less negative when the oxygen content of MWCNTs increased from 0.85% to 7.07% which is consistent with the low adsorption affinity of MWCNTs for atrazine. (c) 2009 Elsevier B.V. All rights reserved. |
WOS记录号 | WOS:000268967200126 |
源URL | [http://ir.rcees.ac.cn/handle/311016/21451] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Chen, Guang-Cai,Shan, Xiao-Quan,Zhou, Yi-Quan,et al. Adsorption kinetics, isotherms and thermodynamics of atrazine on surface oxidized multiwalled carbon nanotubes[J]. JOURNAL OF HAZARDOUS MATERIALS,2009,169(1):912-918. |
APA | Chen, Guang-Cai,Shan, Xiao-Quan,Zhou, Yi-Quan,Shen, Xiu-e,Huang, Hong-Lin,&Khan, Shahamat U..(2009).Adsorption kinetics, isotherms and thermodynamics of atrazine on surface oxidized multiwalled carbon nanotubes.JOURNAL OF HAZARDOUS MATERIALS,169(1),912-918. |
MLA | Chen, Guang-Cai,et al."Adsorption kinetics, isotherms and thermodynamics of atrazine on surface oxidized multiwalled carbon nanotubes".JOURNAL OF HAZARDOUS MATERIALS 169.1(2009):912-918. |
入库方式: OAI收割
来源:生态环境研究中心
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