Ionic liquids as mobile phase additives for high-performance liquid chromatography separation of phenoxy acid herbicides and phenols
文献类型：期刊论文
| 作者 | Hu, Xialin ; Peng, Jinfeng ; Huan, Yuanjian ; Yin, Daqiang ; Liu, Jingfu |
| 刊名 | JOURNAL OF SEPARATION SCIENCE
 |
| 出版日期 | 2009-12 |
| 卷号 | 32期号:23-24页码:4126-4132 |
| 关键词 | High performance liquid chromatography Ionic liquids Ion-pair reagent Phenoxy acid herbicides Phenols |
| 中文摘要 | In this present study, 1-butyl-3-methylimidazolium chloride ([C(4)MIM]Cl), I-octyl-3-methylimidazolium chloride ([C(8)MIM]Cl), and 1-decyl-3-methylimidazolium chloride ([C(10)MIM)Cl) were adopted as mobile phase additives in the high performance liquid chromatography (HPLC) to simultaneously separate phenoxy acid herbicides and phenols at neutral pH. It was found that by using 20 mM of [C(4)MIM]Cl, baseline separation and good chromatograms for all the acid compounds were obtained on a normal reversed-phase C(18) column. The retention time of the target acid compounds shortened with the increase of the alkyl chain length and the concentrations of ionic liquids, probably due to the delocalization of the positive charge on the imidazolium cation, the repulsion between chlorine ions of ionic liquids and the acid compounds, as well as the stereo-hindrance effect. The mechanism with ionic liquids as mobile additives for the separation of acid compounds was discussed. |
| WOS记录号 | WOS:000274217600016 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/21524]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Hu, Xialin,Peng, Jinfeng,Huan, Yuanjian,et al. Ionic liquids as mobile phase additives for high-performance liquid chromatography separation of phenoxy acid herbicides and phenols[J]. JOURNAL OF SEPARATION SCIENCE,2009,32(23-24):4126-4132. |
| APA | Hu, Xialin,Peng, Jinfeng,Huan, Yuanjian,Yin, Daqiang,&Liu, Jingfu.(2009).Ionic liquids as mobile phase additives for high-performance liquid chromatography separation of phenoxy acid herbicides and phenols.JOURNAL OF SEPARATION SCIENCE,32(23-24),4126-4132. |
| MLA | Hu, Xialin,et al."Ionic liquids as mobile phase additives for high-performance liquid chromatography separation of phenoxy acid herbicides and phenols".JOURNAL OF SEPARATION SCIENCE 32.23-24(2009):4126-4132. |
入库方式： OAI收割
来源：生态环境研究中心
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