Study on superoxide and hydroxyl radicals generated in indirect electrochemical oxidation by chemiluminescence and UV-Visible spectra
文献类型：期刊论文
| 作者 | Zhang Bo-Tao ; Zhao Li-Xia ; Lin Jin-Ming |
| 刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
 |
| 出版日期 | 2008 |
| 卷号 | 20期号:8页码:1006-1011 |
| 关键词 | chemiluminescence (CL) UV-Visible radical indirect electrochemical oxidation |
| 英文摘要 | The generation and transformation of radicals on the cathode of indirect electrochemical oxidation were studied by chemiluminescence (CL) and UV-Visible spectra in the reactor with a salt bridge that connected the separated chambers. The CL intensity of 4 x 10(-9) mol/L luminol on the cathode with bubbling oxygen was about seven times that of the intensity without it, which was because of the generation of reactive oxygen species (ROS). The existence of ROS, especially the generation of the superoxide radical, could be affirmed by the fact that the CL intensity of 4 x 10-9 mol/L 2-methyl-6-(4-methoxyphenyl)-3,7-dihydroimidazo[1, 2-a]pyrazin-3-one with bubbling oxygen was about four times that of the intensity without it. However, there was no chemiluminescence on the anode under the same condition. The change in the UV-Visible spectra of nitro blue tetrazolium and N,N-dimethyl-4-nitrosoaniline at the cathode chamber affirmed the transformation from oxygen to superoxide and hydroxyl radicals. The mechanism of the superoxide and hydroxyl radical generation and transformation on the cathode was discussed with the help of the experimental results and relative references. |
| WOS记录号 | WOS:000258460100018 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/21998]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhang Bo-Tao,Zhao Li-Xia,Lin Jin-Ming. Study on superoxide and hydroxyl radicals generated in indirect electrochemical oxidation by chemiluminescence and UV-Visible spectra[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2008,20(8):1006-1011. |
| APA | Zhang Bo-Tao,Zhao Li-Xia,&Lin Jin-Ming.(2008).Study on superoxide and hydroxyl radicals generated in indirect electrochemical oxidation by chemiluminescence and UV-Visible spectra.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,20(8),1006-1011. |
| MLA | Zhang Bo-Tao,et al."Study on superoxide and hydroxyl radicals generated in indirect electrochemical oxidation by chemiluminescence and UV-Visible spectra".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 20.8(2008):1006-1011. |
入库方式： OAI收割
来源：生态环境研究中心
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