Catalytic combustion of methane over La2TM0.3Zr1.7O7-delta (TM = Mn, Fe, and Co) pyrochlore oxides
文献类型:期刊论文
作者 | Cheng, Jie; Li, Jinjun; Ma, Chunyan; Hao, Zhengping |
刊名 | CATALYSIS COMMUNICATIONS
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出版日期 | 2009-03-30 |
卷号 | 10期号:8页码:1170-1173 |
关键词 | Methane Catalytic combustion La2Zr2O7 pyrochlore Transition metal doping |
中文摘要 | La2Zr2O7 and La2TM0.3Zr1.7O7-delta (TM = Fe, Mn, and Co) pyrochlores were investigated as catalysts for methane combustion at moderate-high temperatures. They were prepared by the coprecipitation method and characterized by XRD, DSC, H-2-TPR, IR, and N-2 adsorption/desorption techniques. The introduction of transition metals strongly influences the Zr-O bond strength, the temperature of pyrochlore phase formation, the redox properties, and crystallite size of pyrochlores. Among the catalysts tested, La2Fe0.3Zr1.7O7-delta gives the highest catalytic activity. The catalytic activities of La2TM0.3Zr1.7O7-delta pyrochlore oxides for methane combustion were mainly dependent on the textural properties (BET area, crystallite size). Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved. |
WOS记录号 | WOS:000264975200009 |
源URL | [http://ir.rcees.ac.cn/handle/311016/21605] ![]() |
专题 | 生态环境研究中心_环境纳米材料实验室 |
推荐引用方式 GB/T 7714 | Cheng, Jie,Li, Jinjun,Ma, Chunyan,et al. Catalytic combustion of methane over La2TM0.3Zr1.7O7-delta (TM = Mn, Fe, and Co) pyrochlore oxides[J]. CATALYSIS COMMUNICATIONS,2009,10(8):1170-1173. |
APA | Cheng, Jie,Li, Jinjun,Ma, Chunyan,&Hao, Zhengping.(2009).Catalytic combustion of methane over La2TM0.3Zr1.7O7-delta (TM = Mn, Fe, and Co) pyrochlore oxides.CATALYSIS COMMUNICATIONS,10(8),1170-1173. |
MLA | Cheng, Jie,et al."Catalytic combustion of methane over La2TM0.3Zr1.7O7-delta (TM = Mn, Fe, and Co) pyrochlore oxides".CATALYSIS COMMUNICATIONS 10.8(2009):1170-1173. |
入库方式: OAI收割
来源:生态环境研究中心
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