Fabrication of TiO2/Ti nanotube electrode and the photoelectrochemical behaviors in NaCl solutions
文献类型：期刊论文
| 作者 | Xiao, Shuhu; Qu, Jiuhui; Liu, Huijuan; Zhao, Xu; Wan, Dongjin |
| 刊名 | JOURNAL OF SOLID STATE ELECTROCHEMISTRY
 |
| 出版日期 | 2009-12 |
| 卷号 | 13期号:12页码:1959-1964 |
| 关键词 | TiO2/Ti nanotube electrodes Chloride ion Photoelectrochemical behaviors Active Chlorine Synergetic effect |
| 中文摘要 | Titanium oxide nanotube electrodes were successfully prepared by anodic oxidation on pure Ti sheets in 0.5 wt.% NH4F + 1 wt.% (NH4)(2)SO4 + 90 wt.% glycerol mixed solutions. Nanotubes with diameter 40-60 nm and length 7.4 mu m were observed by field emission scanning electron microscope. The electrochemical and photoelectrochemical characteristics of TiO2 nanotube electrode were investigated using linear polarization and electrochemical impedance spectroscopy techniques. The open-circuit potential dropped markedly under irradiation and with the increase of Cl- concentrations. A saturated photocurrent of approximately 1.3 mA cm(-2) was observed under 10-W low-mercury lamp irradiation in 0.1 M NaCl solution, which was much higher than film electrode. Meanwhile, the highest photocurrent in NaCl solution implied that the photogenerated holes preferred to combine with Cl-. Thus, a significant synergetic effect on active chlorine production was observed in photoelectrocatalytic processes. Furthermore, the generation efficiency for active chlorine was about two times that using TiO2/Ti film electrode by sol-gel method. Finally, the effects of initial pH and Cl- concentration were also discussed. |
| WOS记录号 | WOS:000270872000019 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/21681]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xiao, Shuhu,Qu, Jiuhui,Liu, Huijuan,et al. Fabrication of TiO2/Ti nanotube electrode and the photoelectrochemical behaviors in NaCl solutions[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2009,13(12):1959-1964. |
| APA | Xiao, Shuhu,Qu, Jiuhui,Liu, Huijuan,Zhao, Xu,&Wan, Dongjin.(2009).Fabrication of TiO2/Ti nanotube electrode and the photoelectrochemical behaviors in NaCl solutions.JOURNAL OF SOLID STATE ELECTROCHEMISTRY,13(12),1959-1964. |
| MLA | Xiao, Shuhu,et al."Fabrication of TiO2/Ti nanotube electrode and the photoelectrochemical behaviors in NaCl solutions".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 13.12(2009):1959-1964. |
入库方式： OAI收割
来源：生态环境研究中心
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