Photoassisted degradation of endocrine disruptors over CuOx-FeOOH with H2O2 at neutral pH
文献类型：期刊论文
| 作者 | Nie, Yulun; Hu, Chun; Qu, Jiuhui; Zhao, Xu |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2009-05-16 |
| 卷号 | 87期号:1页码:30-36 |
| 关键词 | Endocrine disruptors CuOx FeOOH Photo-Fenton H2O2 decomposition |
| 中文摘要 | CuOx-doped alpha-FeOOH (CuOx-FeOOH) nanorods were synthesized by controlling the reaction between ferrous sulfate, cupric sulfate and sodium borohydride at ambient atmosphere. The resulting materials were characterized by transmission electron microscopy, X-ray powder diffraction, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. CuOx-FeOOH was mainly composed of alpha-FeOOH and CuOx (CuO and Cu2O). The catalyst was found to be highly effective for the degradation of endocrine disruptors, including dimethyl phthalate, 2,4-dichlorophenoxyacetic acid, and 2,4-dichlorophenol in the presence of H2O2 and UVA at neutral pH. By the total organic carbon and GC-MS analysis, the degradation process of DMP was shown to proceed with the cleavage of C-O bond in ester linkages and the phenyl ring opening into organic acids and CO2. The studies of (OH)-O-center dot formation and cyclic voltammetry revealed that the H2O2 was decomposed into (OH)-O-center dot or O-2 by the promotion of metal oxide. The obtained results showed that the synergistic effect between CuOx and alpha-FeOOH markedly enhanced the H2O2 decomposition into (OH)-O-center dot in CuOx-FeOOH suspension, causing the higher catalytic reactivity. A possible reaction mechanism was proposed. (C) 2008 Published by Elsevier B.V. |
| WOS记录号 | WOS:000264662500004 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/21713]  |
| 专题 | 生态环境研究中心_环境水质学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Nie, Yulun,Hu, Chun,Qu, Jiuhui,et al. Photoassisted degradation of endocrine disruptors over CuOx-FeOOH with H2O2 at neutral pH[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2009,87(1):30-36. |
| APA | Nie, Yulun,Hu, Chun,Qu, Jiuhui,&Zhao, Xu.(2009).Photoassisted degradation of endocrine disruptors over CuOx-FeOOH with H2O2 at neutral pH.APPLIED CATALYSIS B-ENVIRONMENTAL,87(1),30-36. |
| MLA | Nie, Yulun,et al."Photoassisted degradation of endocrine disruptors over CuOx-FeOOH with H2O2 at neutral pH".APPLIED CATALYSIS B-ENVIRONMENTAL 87.1(2009):30-36. |
入库方式： OAI收割
来源：生态环境研究中心
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