Characterization and activity of visible-light-driven TiO2 photocatalyst codoped with nitrogen and cerium
文献类型:期刊论文
作者 | Liu, Chao ; Tang, Xinhu ; Mo, Cehui ; Qiang, Zhimin |
刊名 | JOURNAL OF SOLID STATE CHEMISTRY
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出版日期 | 2008-04 |
卷号 | 181期号:4页码:913-919 |
关键词 | TiO2 photocatalyst codoping nitrogen cerium visible light |
英文摘要 | Nitrogen and cerium codoped TiO2 photocatalysts were prepared by a modified sol-gel process with doping precursors of cerium nitrate and urea, and characterized by X-ray diffraction (XRD), thermogravimetry-differential scanning calorimetry (TG-DSC), X-ray photoelectron spectra (XPS) and ultraviolet-visible light diffuse reflectance spectra (UV-vis DRS). Results indicate that anatase TiO2 is the dominant crystalline type in as-prepared samples, and CeO2 crystallites appear as the doping ratio of Ce/Ti reaches to 3.0 at%. The TiO2 starts to transform from amorphous phase to anatase at 987.1 K during calcination, according to the TG-DSC curves. The XPS show that three major metal ions of Ce3+, Ce4+, Ti4+ and one minor metal ion of Ti3+ coexist on the surface. The codoped TiO2 exhibits significant absorption within the range of 400-500 nm compared to the non-doped and only nitrogen-doped TiO2. The enhanced photocatalytic activity of the codoped TiO2 is demonstrated through degradation of methyl orange under visible light irradiation. (C) 2008 Published by Elsevier Inc. |
WOS记录号 | WOS:000254962800031 |
源URL | [http://ir.rcees.ac.cn/handle/311016/22216] ![]() |
专题 | 生态环境研究中心_环境水质学国家重点实验室 |
推荐引用方式 GB/T 7714 | Liu, Chao,Tang, Xinhu,Mo, Cehui,et al. Characterization and activity of visible-light-driven TiO2 photocatalyst codoped with nitrogen and cerium[J]. JOURNAL OF SOLID STATE CHEMISTRY,2008,181(4):913-919. |
APA | Liu, Chao,Tang, Xinhu,Mo, Cehui,&Qiang, Zhimin.(2008).Characterization and activity of visible-light-driven TiO2 photocatalyst codoped with nitrogen and cerium.JOURNAL OF SOLID STATE CHEMISTRY,181(4),913-919. |
MLA | Liu, Chao,et al."Characterization and activity of visible-light-driven TiO2 photocatalyst codoped with nitrogen and cerium".JOURNAL OF SOLID STATE CHEMISTRY 181.4(2008):913-919. |
入库方式: OAI收割
来源:生态环境研究中心
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