Preparation and characterization of graft copolymer from dealkaline lignin and styrene
文献类型：期刊论文
| 作者 | Li HF(李海峰)1 ; Zhang QS(张勤生)1; Gao P(高平)2; Wang LL(王来来)1; Gao P(高平); Wang LL(王来来)
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| 刊名 | Journal of Applied Polymer Science
 |
| 出版日期 | 2015 |
| 卷号 | 132期号:17页码:41900(1-9) |
| 关键词 | catalysts copolymers grafting polystyrene |
| ISSN号 | 0021-8995 |
| 通讯作者 | 王来来 ; 高平 |
| 英文摘要 | Graft copolymerization of styrene onto dealkaline lignin by ferrous chloride and hydrogen peroxide coinitiator has been achieved successfully. The influence of temperature and reaction time as well as the amount of the styrene monomer, initiator, and catalyst on the grafting copolymerization was investigated. The optimum reaction conditions were determined as follows: c (styrene)=20.00 mmol, c (H2O2)=5.00 mmol, c (FeCl2)=0.10 mmol, T=30 degrees C and t=48 h. The optimum yield (Y), total conversion (TC), grafting efficiency (GE), and degree grafted (DG) values were 96.6, 96.3, 59.5, and 53.7%, respectively. The copolymer of lignin grafted PS was separated and characterized by elemental analysis, differential scanning calorimetry, Fourier transform infrared, thermogravimetry analysis, field emission-scanning electron microscopy, gel permeation chromatography, and nuclear magnetic resonance. It was demonstrated that the solubility what the copolymer exhibited turned out to be the very reverse of the original lignin. The surface properties and structure of lignin were completely changed after grafting copolymerization. |
| 学科主题 | 有机功能材料 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 21174155);the Youth Foundation of Gassu Province (No. 145RJYA263) |
| 语种 | 英语 |
| WOS记录号 | WOS:000349384800028 |
| 源URL | [http://210.77.64.217/handle/362003/8184]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
| 通讯作者 | Gao P(高平); Wang LL(王来来) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li HF,Zhang QS,Gao P,et al. Preparation and characterization of graft copolymer from dealkaline lignin and styrene[J]. Journal of Applied Polymer Science,2015,132(17):41900(1-9). |
| APA | Li HF,Zhang QS,Gao P,Wang LL,高平,&王来来.(2015).Preparation and characterization of graft copolymer from dealkaline lignin and styrene.Journal of Applied Polymer Science,132(17),41900(1-9). |
| MLA | Li HF,et al."Preparation and characterization of graft copolymer from dealkaline lignin and styrene".Journal of Applied Polymer Science 132.17(2015):41900(1-9). |
入库方式： OAI收割
来源：兰州化学物理研究所
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