VOx promoted Ni catalysts supported on the modified bentonite for CO and CO2 methanation
文献类型：期刊论文
| 作者 | Lu, Xiaopeng1,2; Gu, Fangna2; Liu, Qing2; Gao, Jiajian2; Liu, Youjun1,2; Li, Huifang2; Jia, Lihua1; Xu, Guangwen2; Zhong, Ziyi3; Su, Fabing2 |
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2015-07-01 |
| 卷号 | 135期号:JUL页码:34-46 |
| 关键词 | CO methanation CO2 methanation SNG Macro-mesoporous Bentonite VOx |
| ISSN号 | 0378-3820 |
| 英文摘要 | Ni catalysts supported on the raw bentonite (RB) and the acid-alkali treated bentonite (B), which were prepared by the impregnation method, were tested for methanation of CO2 and CO respectively to produce synthetic natural gas (SNG). XRD, nitrogen adsorption, SEM, TEM, TG, H-2-TPR, and XPS were employed for the characterization of the samples. The results showed that the Ni catalysts supported on the B support were more active than that supported on the RB support because of the improved Ni particles dispersion on the former that had larger specific surface area. After addition of proper amount of the VOx promoter, the catalytic activity of the B supported catalysts was further improved. This could be attributed to the enhanced H-2 uptakes, increased Ni dispersion, reduced Ni nanoparticle size, and the electronic effect of VOx that can promote dissociation of CO in the methanation reaction. In the lifetime test of CO2 and CO methanation under atmospheric pressure, the Ni/B catalysts promoted by the VOx promoter were highly stable as they had superior anti-coking and anti-sintering performance to the catalyst without the promoter. This type of the catalysts is promising for industrial production of SNG. (C) 2014 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Chemistry ; Energy & Fuels ; Engineering |
| 关键词[WOS] | SYNTHETIC NATURAL-GAS ; CARBON-DIOXIDE ; NICKEL-CATALYSTS ; NI/AL2O3 CATALYSTS ; OXIDES ; HYDROGENATION ; VANADIUM ; SYNGAS ; PERFORMANCE ; DEPOSITION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355371100007 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/19255]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Heilongjiang Pr, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.ASTAR, Inst Chem Engn & Sci, Singapore 627833, Singapore |
| 推荐引用方式 GB/T 7714 | Lu, Xiaopeng,Gu, Fangna,Liu, Qing,et al. VOx promoted Ni catalysts supported on the modified bentonite for CO and CO2 methanation[J]. FUEL PROCESSING TECHNOLOGY,2015,135(JUL):34-46. |
| APA | Lu, Xiaopeng.,Gu, Fangna.,Liu, Qing.,Gao, Jiajian.,Liu, Youjun.,...&Su, Fabing.(2015).VOx promoted Ni catalysts supported on the modified bentonite for CO and CO2 methanation.FUEL PROCESSING TECHNOLOGY,135(JUL),34-46. |
| MLA | Lu, Xiaopeng,et al."VOx promoted Ni catalysts supported on the modified bentonite for CO and CO2 methanation".FUEL PROCESSING TECHNOLOGY 135.JUL(2015):34-46. |
入库方式： OAI收割
来源：过程工程研究所
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