Kinetics of the decomposition of dimethylhexane-1,6-dicarbamate to 1,6-hexamethylene diisocyanate
文献类型：期刊论文
| 作者 | Cao, Yan; Li, Huiquan; Qin, Ningbo; Zhu, Ganyu |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2015-05-01 |
| 卷号 | 23期号:5页码:775-779 |
| 关键词 | Kinetics 1,6-Hexamethylene diisocyanate Decomposition Dimethylhexane-1,6-dicarbamate |
| ISSN号 | 1004-9541 |
| 英文摘要 | The kinetics of the decomposition of dimethylhexane-1,6-dicarbamate to 1,6-hexamethylene diisocyanate was studied. A consecutive reaction model was established and the reaction orders for the two steps were confirmed to be 1 and 1.3 by the integral test method and the numerical differential method, respectively. The activation energies of the two steps were (56.94 +/- 5.90) kJ center dot mol(-1) and (72.07 +/- 3.47) kJ center dot mol(-1) with the frequency factors exp(12.53 +/- 1.42) min(-1) and (14.254 +/- 0.84) mol(-0.33) center dot L-0.33 center dot min(-1), respectively. Based on the kinetic model obtained, the progress of the reaction can be calculated under given conditions. (C) 2015 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Engineering, Chemical |
| 研究领域[WOS] | Engineering |
| 关键词[WOS] | DIMETHYL CARBONATE ; METHOXYCARBONYLATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000356309300004 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/19273]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Yan,Li, Huiquan,Qin, Ningbo,et al. Kinetics of the decomposition of dimethylhexane-1,6-dicarbamate to 1,6-hexamethylene diisocyanate[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2015,23(5):775-779. |
| APA | Cao, Yan,Li, Huiquan,Qin, Ningbo,&Zhu, Ganyu.(2015).Kinetics of the decomposition of dimethylhexane-1,6-dicarbamate to 1,6-hexamethylene diisocyanate.CHINESE JOURNAL OF CHEMICAL ENGINEERING,23(5),775-779. |
| MLA | Cao, Yan,et al."Kinetics of the decomposition of dimethylhexane-1,6-dicarbamate to 1,6-hexamethylene diisocyanate".CHINESE JOURNAL OF CHEMICAL ENGINEERING 23.5(2015):775-779. |
入库方式： OAI收割
来源：过程工程研究所
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