A polyazamacrocycle extractant for the extraction of americium and europium
文献类型：期刊论文
| 作者 | Pan, Dengfang1; Jia, Cai2; He, Xihong1; Ye, Gang1; Chen, Jing1 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2015-06-01 |
| 卷号 | 58期号:6页码:986-992 |
| 关键词 | polyazamacrocycle extractant americium europium extraction |
| ISSN号 | 1674-7291 |
| 英文摘要 | In recent years, a great deal of interest has been focused on nitrogen-containing extractants for the separation of actinides from lanthanides. In this study, we synthesized a polyazamacrocycle-type C-8-cyclen ligand comprising four tertiary alkyl amino groups, for the extraction of Am3+ and Eu3+. The C-8-cyclen demonstrated a weak ability to extract and separate Am3+ and Eu3+ that increased with the increasing "softness" of the aqueous anions. The extraction behavior of Am3+ and Eu3+ indicated coordination interactions between the C-8-cyclen and the Am3+ and Eu3+ ions. The suppression of Am3+ or Eu3+ extraction by acid depended on the media anions involved. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | SELECTIVE EXTRACTION ; SOLVENT-EXTRACTION ; METAL CATIONS ; SEPARATION ; COMPLEXES ; AM(III) ; ACTINIDES ; LIGAND ; EU(III) ; ACID |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000355266100012 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/19262]  |
| 专题 | 过程工程研究所_研究所（批量导入） |
| 作者单位 | 1.Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pan, Dengfang,Jia, Cai,He, Xihong,et al. A polyazamacrocycle extractant for the extraction of americium and europium[J]. SCIENCE CHINA-CHEMISTRY,2015,58(6):986-992. |
| APA | Pan, Dengfang,Jia, Cai,He, Xihong,Ye, Gang,&Chen, Jing.(2015).A polyazamacrocycle extractant for the extraction of americium and europium.SCIENCE CHINA-CHEMISTRY,58(6),986-992. |
| MLA | Pan, Dengfang,et al."A polyazamacrocycle extractant for the extraction of americium and europium".SCIENCE CHINA-CHEMISTRY 58.6(2015):986-992. |
入库方式： OAI收割
来源：过程工程研究所
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