Dechlorination of hexachlorobenzene over Mg-Fe composite oxides
文献类型:期刊论文
作者 | Ma, Xiaodong ; Sun, Hongwen ; Liu, Wenbin ; Liu, Wenxia ; Zheng, Minghui |
刊名 | FRESENIUS ENVIRONMENTAL BULLETIN
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出版日期 | 2007 |
卷号 | 16期号:7页码:745-748 |
关键词 | dechlorination Mg-Fe composite oxides coprecipitation HCB MgFe2O4 hydrodechlorination |
英文摘要 | Mg-Fe composite oxides with different Mg/Fe atomic ratios were synthesized by co-precipitation and characterized by X-ray diffraction (XRD). Their dechlorination activities were evaluated using hexachlorobenzene (HCB) as a model compound. The experiments were carried out at 300 degrees C for 0.5 h. The results indicate that the Mg-Fe composite oxide (Mg/Fe atomic ratio was 8) exhibits the best dechlorination activity among the oxides examined. This may be related to the formation of MgFe2O4 phase with small crystal size. The products after reaction were analyzed by GCMS, XRD, and a chloride selective electrode. It was found that hydrodechlorination took place in the destruction of HCB. The discrepancy in the material balance between starting material and dechlorinated products indicates that, in addition to hydrodechlorination, other degradation routes may be present. |
WOS记录号 | WOS:000248571800006 |
源URL | [http://ir.rcees.ac.cn/handle/311016/22431] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Ma, Xiaodong,Sun, Hongwen,Liu, Wenbin,et al. Dechlorination of hexachlorobenzene over Mg-Fe composite oxides[J]. FRESENIUS ENVIRONMENTAL BULLETIN,2007,16(7):745-748. |
APA | Ma, Xiaodong,Sun, Hongwen,Liu, Wenbin,Liu, Wenxia,&Zheng, Minghui.(2007).Dechlorination of hexachlorobenzene over Mg-Fe composite oxides.FRESENIUS ENVIRONMENTAL BULLETIN,16(7),745-748. |
MLA | Ma, Xiaodong,et al."Dechlorination of hexachlorobenzene over Mg-Fe composite oxides".FRESENIUS ENVIRONMENTAL BULLETIN 16.7(2007):745-748. |
入库方式: OAI收割
来源:生态环境研究中心
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