Determination of riboflavin by enhancing the chemiluminescence intensity of peroxomonosulfate-cobalt(II) system
文献类型：期刊论文
| 作者 | Wang, Min; Zhao, Lixia; Liu, Meilin; Lin, Jin-Ming |
| 刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2007-04 |
| 卷号 | 66期号:1页码:1222-1227 |
| 关键词 | chemiluminescence peroxomonosulfate riboflavin cobalt (II) flow injection analysis (FIA) |
| 英文摘要 | A weak chemiluminescent (CL) emission was observed in the decomposition of peroxomonosulfate (HSO5-), which would be accelerated in the presence of trace amounts of cobalt (II). The mechanism was due to the production of singlet oxygen (O-1(2)). Interestedly, riboflavin can enhance the CL and the CL intensity was strongly dependent on riboflavin concentration. Based on this phenomenon, a flow injection analysis (FIA) CL method was established for the determination of riboflavin. Additionally, the possible CL mechanism is proposed based on the kinetic curve of the CL reaction, CL spectra, UV-vis spectra and fluorescent spectra. The CL intensity was correlated linearly with concentration of riboflavin over the range of 1.0 x 10(-4) to 1.0 x 10(-8) g mL(-1); the detection limit was 9.0 x 10(-9) g mL(-1) (S/N = 3); the relative standard deviation was 1.4% for 9 x 10(-7) g mL(-1) riboflavin (n = 11). Furthermore, this method was applied to the determination of riboflavin in real tablets and injections successfully. (c) 2006 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000245480400067 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/22437]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang, Min,Zhao, Lixia,Liu, Meilin,et al. Determination of riboflavin by enhancing the chemiluminescence intensity of peroxomonosulfate-cobalt(II) system[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2007,66(1):1222-1227. |
| APA | Wang, Min,Zhao, Lixia,Liu, Meilin,&Lin, Jin-Ming.(2007).Determination of riboflavin by enhancing the chemiluminescence intensity of peroxomonosulfate-cobalt(II) system.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,66(1),1222-1227. |
| MLA | Wang, Min,et al."Determination of riboflavin by enhancing the chemiluminescence intensity of peroxomonosulfate-cobalt(II) system".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 66.1(2007):1222-1227. |
入库方式： OAI收割
来源：生态环境研究中心
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