Synthesis of sporiolide B from D-glucal
文献类型:期刊论文
作者 | Chen, Qi ; Du, Yuguo |
刊名 | CARBOHYDRATE RESEARCH
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出版日期 | 2007-08-13 |
卷号 | 342期号:11页码:1405-1411 |
关键词 | total synthesis macrolides sporiolide B D-glucal natural products |
英文摘要 | A total synthesis of the 12-membered ring natural macrolide, sporiolide B, was achieved from D-glucal in 17 steps with 4.8% overall yield. The required stereochemical configuration at C-3 and C-5 in sporiolide B was easily introduced by applying a Mitsunobu reaction on the chiral template D-glucal. Yamaguchi esterification and ring closing metathesis greatly improved the access to the target compound. (c) 2007 Elsevier Ltd. All rights reserved. |
WOS记录号 | WOS:000248370800002 |
源URL | [http://ir.rcees.ac.cn/handle/311016/22511] ![]() |
专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
推荐引用方式 GB/T 7714 | Chen, Qi,Du, Yuguo. Synthesis of sporiolide B from D-glucal[J]. CARBOHYDRATE RESEARCH,2007,342(11):1405-1411. |
APA | Chen, Qi,&Du, Yuguo.(2007).Synthesis of sporiolide B from D-glucal.CARBOHYDRATE RESEARCH,342(11),1405-1411. |
MLA | Chen, Qi,et al."Synthesis of sporiolide B from D-glucal".CARBOHYDRATE RESEARCH 342.11(2007):1405-1411. |
入库方式: OAI收割
来源:生态环境研究中心
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