Thiolsulfonate functionalized polystyrene resin: Preparation and application in the isolation and identification of electrophilic mutagens
文献类型：期刊论文
| 作者 | Wu E; Carlson, Robert M. |
| 刊名 | JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
 |
| 出版日期 | 2007 |
| 卷号 | 19期号:12页码:1520-1527 |
| 关键词 | functionalized polystyrene potassium polystyryl-thiosulfonate unsymmetrical ethyl disulfides electrophilic mutagens |
| 英文摘要 | A new approach for isolation and identification of elecrtophilic mutagens from complex matrix was developed. Thiosulfonic anion was immobilized onto polystyrene beads and used as separation media. Potassium polystyryl-thiosulfonate, prepared from polystyryl-sulfonyl chloride and KHS, was observed to selectively react with model electrophilic mutagens such as alkyl halides, alpha-chloroketones and alpha-chloroesters to produce polystyryl-thiosulfonic esters. After separation from other nonreactive organic compounds, the beads then reacted with ethanethiol to produce unsymmetrical ethyl disulfides which are easily detected by GC/MS. For one mutagenic compound, only one unsymmetrical disulfide was found to contain its structure part. Thus, the structure of the parent mutagens could be deduced from that of the unsymmetrical disulfides. The degree of functionalization of the potassium polystyryl-thiosulfonate resin was 1.11 mmol/g. Its reactivity was discussed and its recycling method was reported here. |
| WOS记录号 | WOS:000252292300019 |
| 源URL | [http://ir.rcees.ac.cn/handle/311016/22514]  |
| 专题 | 生态环境研究中心_环境化学与生态毒理学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wu E,Carlson, Robert M.. Thiolsulfonate functionalized polystyrene resin: Preparation and application in the isolation and identification of electrophilic mutagens[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2007,19(12):1520-1527. |
| APA | Wu E,&Carlson, Robert M..(2007).Thiolsulfonate functionalized polystyrene resin: Preparation and application in the isolation and identification of electrophilic mutagens.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,19(12),1520-1527. |
| MLA | Wu E,et al."Thiolsulfonate functionalized polystyrene resin: Preparation and application in the isolation and identification of electrophilic mutagens".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 19.12(2007):1520-1527. |
入库方式： OAI收割
来源：生态环境研究中心
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