Deactivation mechanism of nanosized gold catalysts stored in ambient air
文献类型:期刊论文
作者 | Wang Donghui ; Dong Tongxin ; Shi Xicheng ; Hao Zhengping |
刊名 | CHINESE JOURNAL OF CATALYSIS
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出版日期 | 2007-02 |
卷号 | 28期号:2页码:148-152 |
关键词 | nanoparticle gold zinc oxide supported catalyst carbon monoxide oxidation deactivation mechanism carbonate |
英文摘要 | A nanosized 2.5% Au/ZnO catalyst was prepared using the coprecipitation method at low temperature. The deactivation mechanism of the catalyst stored in ambient air was investigated using scanning transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The deactivation of the catalyst was partially reversible, and two factors interrelated the deactivation. One was the agglomeration of nanosized gold particles, which caused the irreversible deactivation. The other was the accumulation of carbonates on the catalyst surface, leading to the reversible deactivation. The carbonates could be decomposed when the deactivated catalyst was calcined at high temperature. |
WOS记录号 | WOS:000244994000012 |
源URL | [http://ir.rcees.ac.cn/handle/311016/22519] ![]() |
专题 | 生态环境研究中心_环境纳米材料实验室 |
推荐引用方式 GB/T 7714 | Wang Donghui,Dong Tongxin,Shi Xicheng,et al. Deactivation mechanism of nanosized gold catalysts stored in ambient air[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(2):148-152. |
APA | Wang Donghui,Dong Tongxin,Shi Xicheng,&Hao Zhengping.(2007).Deactivation mechanism of nanosized gold catalysts stored in ambient air.CHINESE JOURNAL OF CATALYSIS,28(2),148-152. |
MLA | Wang Donghui,et al."Deactivation mechanism of nanosized gold catalysts stored in ambient air".CHINESE JOURNAL OF CATALYSIS 28.2(2007):148-152. |
入库方式: OAI收割
来源:生态环境研究中心
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