中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Deactivation mechanism of nanosized gold catalysts stored in ambient air

文献类型:期刊论文

作者Wang Donghui ; Dong Tongxin ; Shi Xicheng ; Hao Zhengping
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2007-02
卷号28期号:2页码:148-152
关键词nanoparticle gold zinc oxide supported catalyst carbon monoxide oxidation deactivation mechanism carbonate
英文摘要A nanosized 2.5% Au/ZnO catalyst was prepared using the coprecipitation method at low temperature. The deactivation mechanism of the catalyst stored in ambient air was investigated using scanning transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The deactivation of the catalyst was partially reversible, and two factors interrelated the deactivation. One was the agglomeration of nanosized gold particles, which caused the irreversible deactivation. The other was the accumulation of carbonates on the catalyst surface, leading to the reversible deactivation. The carbonates could be decomposed when the deactivated catalyst was calcined at high temperature.
WOS记录号WOS:000244994000012
源URL[http://ir.rcees.ac.cn/handle/311016/22519]  
专题生态环境研究中心_环境纳米材料实验室
推荐引用方式
GB/T 7714
Wang Donghui,Dong Tongxin,Shi Xicheng,et al. Deactivation mechanism of nanosized gold catalysts stored in ambient air[J]. CHINESE JOURNAL OF CATALYSIS,2007,28(2):148-152.
APA Wang Donghui,Dong Tongxin,Shi Xicheng,&Hao Zhengping.(2007).Deactivation mechanism of nanosized gold catalysts stored in ambient air.CHINESE JOURNAL OF CATALYSIS,28(2),148-152.
MLA Wang Donghui,et al."Deactivation mechanism of nanosized gold catalysts stored in ambient air".CHINESE JOURNAL OF CATALYSIS 28.2(2007):148-152.

入库方式: OAI收割

来源:生态环境研究中心

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