Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes
文献类型：期刊论文
| 作者 | Ren, Yun-Lai1; Shang, Huantao1; Wang, Jianji1,2; Tian, Xinzhe1; Zhao, Shuang1; Wang, Qian1; Li FW(李福伟)3
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| 刊名 | Advanced Synthesis and Catalysis
 |
| 出版日期 | 2013 |
| 卷号 | 355期号:17页码:3437-3442 |
| 关键词 | arenes catalysis iodination nitrogen dioxide |
| ISSN号 | 1615-4150 |
| 通讯作者 | Jianji Wang |
| 英文摘要 | Nitrogen dioxide is demonstrated to be an effective catalyst precursor for the iodination of alkoxy-substituted benzenes and naphthalenes. Different from the transition metal catalysts, nitrogen dioxide can be easily separated from the final products, and is free of heavy metal waste. Although the present catalyst precursor is toxic, it does not stain the final products due to its low-boiling character. No other reagents apart from 0.5equiv. of iodine (I-2), 6.5mol% nitrogen dioxide and acetonitrile solvent were used in the iodination, and basically all the iodine atoms in the iodine source were transferred to the iodination products, showing that the presented protocol is highly atom-economic and practical. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Grant No. 21002023);the National Basic Research Program of China (975 Program, Grant No. 2011CB211702) |
| 语种 | 英语 |
| WOS记录号 | WOS:000327984000018 |
| 源URL | [http://210.77.64.217/handle/362003/12390]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China 2.Henan Normal Univ, Sch Chem & Chem Engn, Key Lab Green Chem Media & React, Minist Educ, Xinxiang 453007, Henan, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Yun-Lai,Shang, Huantao,Wang, Jianji,et al. Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes[J]. Advanced Synthesis and Catalysis,2013,355(17):3437-3442. |
| APA | Ren, Yun-Lai.,Shang, Huantao.,Wang, Jianji.,Tian, Xinzhe.,Zhao, Shuang.,...&Li FW.(2013).Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes.Advanced Synthesis and Catalysis,355(17),3437-3442. |
| MLA | Ren, Yun-Lai,et al."Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes".Advanced Synthesis and Catalysis 355.17(2013):3437-3442. |
入库方式： OAI收割
来源：兰州化学物理研究所
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