Immobilization of a non-aqueous soluble probe onto mesoporous silica for utilization in highly sensitive and selective detection and removal of Hg2+ in pure aqueous media
文献类型：期刊论文
| 作者 | Zhou, Huangxin ; Zhang, Ling ; Liang, Zhenhua ; Peng, Guihua ; Lin, Hengwei |
| 刊名 | DYES AND PIGMENTS
 |
| 出版日期 | 2014 |
| 卷号 | 111页码:52 |
| 中文摘要 | An efficient strategy to immobilize a non-aqueous soluble Hg2+ probe onto mesoporous silica is developed, and this immobilization is subject to several advantages regarding Hg2+ detection, such as improving sensing sensitivity and selectivity, extending application from an organic/aqueous mixture to a pure aqueous medium, and achieving removal of Hg2+ ions while detection. The selected Hg2+ probe, rhodamine B thiohydrazide, can be readily covalently immobilized onto mesoporous silica through a simple amide reaction and subsequently exhibits more than 10 times enhancement of sensitivity for Hg2+ (limits of detection are of 0.81 ppb in immobilized form versus 10 ppb in free form), and an adsorption capacity of 192 mg/g. Brunauer-Emmett-Teller and TEM characterizations demonstrate that the mesoporous structure can be well remained after Hg2+ probe modification and this feature is believed to be responsible for improved Hg2+ sensing properties. (C) 2014 Elsevier Ltd. All rights reserved. |
| 公开日期 | 2015-09-20 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/11676]  |
| 专题 | 宁波材料技术与工程研究所_2014专题 |
| 推荐引用方式 GB/T 7714 | Zhou, Huangxin,Zhang, Ling,Liang, Zhenhua,et al. Immobilization of a non-aqueous soluble probe onto mesoporous silica for utilization in highly sensitive and selective detection and removal of Hg2+ in pure aqueous media[J]. DYES AND PIGMENTS,2014,111:52. |
| APA | Zhou, Huangxin,Zhang, Ling,Liang, Zhenhua,Peng, Guihua,&Lin, Hengwei.(2014).Immobilization of a non-aqueous soluble probe onto mesoporous silica for utilization in highly sensitive and selective detection and removal of Hg2+ in pure aqueous media.DYES AND PIGMENTS,111,52. |
| MLA | Zhou, Huangxin,et al."Immobilization of a non-aqueous soluble probe onto mesoporous silica for utilization in highly sensitive and selective detection and removal of Hg2+ in pure aqueous media".DYES AND PIGMENTS 111(2014):52. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。