中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp

文献类型:期刊论文

作者Zhang, Tao ; Chen, Tao ; Amin, Ihsan ; Jordan, Rainer
刊名POLYMER CHEMISTRY
出版日期2014
卷号5期号:16页码:4790
中文摘要Photoinduced atom transfer radical polymerization (ATRP) was achieved using a simple household fluorescent lamp as the light source. In solution, methyl methacrylate could be polymerized to well-defined polymers; the photoinduced ATRP system did only convert monomers during irradiation and was inactive in the dark. In situ monitoring by UV-vis spectroscopy revealed the photoredox cycle between Cu-II and Cu-I species. The linear development of the polymer number average molar mass with monomer conversion, the low dispersity as well as chain extension experiments showed the controlled nature of the polymerization. Photoinduced ATRP was also used to prepare homo- and block copolymer brushes and patterned brushes on surfaces by photoinduced surface-initiated ATRP (PSI-ATRP).
公开日期2015-09-20
源URL[http://ir.nimte.ac.cn/handle/174433/11783]  
专题宁波材料技术与工程研究所_2014专题
推荐引用方式
GB/T 7714
Zhang, Tao,Chen, Tao,Amin, Ihsan,et al. ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp[J]. POLYMER CHEMISTRY,2014,5(16):4790.
APA Zhang, Tao,Chen, Tao,Amin, Ihsan,&Jordan, Rainer.(2014).ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp.POLYMER CHEMISTRY,5(16),4790.
MLA Zhang, Tao,et al."ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp".POLYMER CHEMISTRY 5.16(2014):4790.

入库方式: OAI收割

来源:宁波材料技术与工程研究所

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