ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp
文献类型:期刊论文
作者 | Zhang, Tao ; Chen, Tao ; Amin, Ihsan ; Jordan, Rainer |
刊名 | POLYMER CHEMISTRY
![]() |
出版日期 | 2014 |
卷号 | 5期号:16页码:4790 |
中文摘要 | Photoinduced atom transfer radical polymerization (ATRP) was achieved using a simple household fluorescent lamp as the light source. In solution, methyl methacrylate could be polymerized to well-defined polymers; the photoinduced ATRP system did only convert monomers during irradiation and was inactive in the dark. In situ monitoring by UV-vis spectroscopy revealed the photoredox cycle between Cu-II and Cu-I species. The linear development of the polymer number average molar mass with monomer conversion, the low dispersity as well as chain extension experiments showed the controlled nature of the polymerization. Photoinduced ATRP was also used to prepare homo- and block copolymer brushes and patterned brushes on surfaces by photoinduced surface-initiated ATRP (PSI-ATRP). |
公开日期 | 2015-09-20 |
源URL | [http://ir.nimte.ac.cn/handle/174433/11783] ![]() |
专题 | 宁波材料技术与工程研究所_2014专题 |
推荐引用方式 GB/T 7714 | Zhang, Tao,Chen, Tao,Amin, Ihsan,et al. ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp[J]. POLYMER CHEMISTRY,2014,5(16):4790. |
APA | Zhang, Tao,Chen, Tao,Amin, Ihsan,&Jordan, Rainer.(2014).ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp.POLYMER CHEMISTRY,5(16),4790. |
MLA | Zhang, Tao,et al."ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp".POLYMER CHEMISTRY 5.16(2014):4790. |
入库方式: OAI收割
来源:宁波材料技术与工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。