Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid
文献类型：期刊论文
| 作者 | Ma SongQi ; Liu XiaoQing ; Jiang YanHua ; Fan LiBo ; Feng JianXiang ; Zhu Jin |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2014 |
| 卷号 | 57期号:3页码:379 |
| 中文摘要 | A phosphorus-containing bio-based epoxy resin (EADI) was synthesized from itaconic acid (IA) and 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO). As a matrix, its cured epoxy network with methyl hexahydrophthalic anhydride (MHHPA) as the curing agent showed comparable glass-transition temperature and mechanical properties to diglycidyl ether in a bisphenol A (DGEBA) system as well as good flame retardancy with UL94 V-0 grade during a vertical burning test. As a reactive flame retardant, its flame-resistant effect on DGEBA/MHHPA system as well as its influence on the curing behavior and the thermal and mechanical properties of the modified epoxy resin were investigated. Results showed that after the introduction of EADI, not only were the flame retardancy determined by vertical burning test, LOI measurement, and thermogravimetric analysis significantly improved, but also the curing reactivity, glass transition temperature (T (g)), initial degradation temperature for 5% weight loss (T (d(5%))), and flexural modulus of the cured system improved as well. EADI has great potential to be used as a green flame retardant in epoxy resin systems. |
| 公开日期 | 2015-09-20 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/11919]  |
| 专题 | 宁波材料技术与工程研究所_2014专题 |
| 推荐引用方式 GB/T 7714 | Ma SongQi,Liu XiaoQing,Jiang YanHua,et al. Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid[J]. SCIENCE CHINA-CHEMISTRY,2014,57(3):379. |
| APA | Ma SongQi,Liu XiaoQing,Jiang YanHua,Fan LiBo,Feng JianXiang,&Zhu Jin.(2014).Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid.SCIENCE CHINA-CHEMISTRY,57(3),379. |
| MLA | Ma SongQi,et al."Synthesis and properties of phosphorus-containing bio-based epoxy resin from itaconic acid".SCIENCE CHINA-CHEMISTRY 57.3(2014):379. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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