Synthesis and Photoelectricity of Novel Zn Metal Complex Based on 8-Hydroxyquinoline with Thiophene Group
文献类型：期刊论文
| 作者 | Tang Yinmin ; Huo Yanping ; Hu Sheng ; Zhang Kun ; Zhao Fenghua ; Ouyang Xinhua |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2014 |
| 卷号 | 35期号:1页码:48 |
| 中文摘要 | 8-Hydroxyquinoline has long been employed as analytical and separating agents,due to its universal chelating ability offered by the heterocyclic N and phenolate O atoms and fluorescent property possessed by the conjugate system. In order to increase its fluorescence capability and conjugate system, 3-thiophene has been added. A novel 8-hydroxyquinoline derivative ligand containing thiophene group (E)-2-[2-(3-thiophenyl) ethenyl]-8-hydroxyquinoline (4) and its corresponding zinc complex (5) were synthesized and identified via H-1 NMR, FTIR, UV-Vis, X-ray structural analysis and elemental analyses. The crystal structures of intermediate (E)-2-[2-(3-thiophenyl) ethenyl]-8-acetoxyquinoline (3) and ligand 4 were characterized by single-crystal X-ray diffraction. X-Ray structural analysis showed that there was no obvious hydrogen-bonding interaction between the molecules of compound 3. The crystal reticular structure of compound 4 was constructed as a result of intermolecular O-H center dot center dot center dot S hydrogen bonds. The aggregation behaviors of zinc salts and compound 4 in solutions were investigated with a variety of techniques, including H-1 NMR, UV-Vis and fluorescence. The fluorescence lifetime of complex 5 was determined in the solid state and its tau value is 18. 8 ms. Organic light-emitting diodes built using complex 5 emitted yellow light, in which the 1,3,5-tris(1-phenyl-1H-benzimidazol-2-yl)benzene(TPBi) acts as the electronic transmission layer, while N,N'-bis-(1-naphthalenyl)-N,N'-bisphenyl-(1,1'-biphenyl)-4,4'-diamine(NPB) acts as hole transport material. |
| 公开日期 | 2015-09-20 |
| 源URL | [http://ir.nimte.ac.cn/handle/174433/11963]  |
| 专题 | 宁波材料技术与工程研究所_2014专题 |
| 推荐引用方式 GB/T 7714 | Tang Yinmin,Huo Yanping,Hu Sheng,et al. Synthesis and Photoelectricity of Novel Zn Metal Complex Based on 8-Hydroxyquinoline with Thiophene Group[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2014,35(1):48. |
| APA | Tang Yinmin,Huo Yanping,Hu Sheng,Zhang Kun,Zhao Fenghua,&Ouyang Xinhua.(2014).Synthesis and Photoelectricity of Novel Zn Metal Complex Based on 8-Hydroxyquinoline with Thiophene Group.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,35(1),48. |
| MLA | Tang Yinmin,et al."Synthesis and Photoelectricity of Novel Zn Metal Complex Based on 8-Hydroxyquinoline with Thiophene Group".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 35.1(2014):48. |
入库方式： OAI收割
来源：宁波材料技术与工程研究所
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