Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina
文献类型：期刊论文
| 作者 | Zhu Xu-Fei1; Han Hua2 ; Ma Hong-Tu2; Lu Chao1; Qi Wei-Xing1; Xu Chen1
|
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 28期号:11页码:2648-2658 |
| 关键词 | Nanoporous material Anodization Electrolyte Reducer Formation mechanism |
| 英文摘要 | In recent years, attention has been focused on adjustment and control of the nanostructures of porous anodic alumina (PAA) and porous anodic TiO2 nanotubes (PATNT). Because the formation mechanism of PAA and PATNT is still unclear, it is difficult to adjust the nanostructures of PAA and PATNT. To validate the novel viewpoint of the nanopore resulting from an oxygen bubble mold, an innovative chemical approach was used to adjust the PAA nanostructures. One successful approach is to use a reducer to absorb the oxygen bubbles in the nanopores. A novel anodic alumina film was obtained in a mixed solution of the reducer and oxalic acid. The influence of the reducer on the PAA nanostructures which formed in H3PO4 solution was investigated in detail. The experimental results showed that the regularity and the diameters of the nanopores in the PAA decreased as the reducer content increased. The differences in the voltage-time curves between electrolytes with and without the reducer were analyzed quantitatively. The results showed that the conductivity of the anodic oxide film that formed in the electrolyte with the reducer was better than that in the electrolyte without the reducer. When aluminum anodizes in a sealed case, oxygen bubbles are easily absorbed by the reducer, the oxygen bubble mold effect disappears, and a compact alumina film is obtained. Overall, these results clearly demonstrate that nanopores result from the oxygen bubble mold effect. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | TIO2 NANOTUBE ARRAYS ; FORMATION MECHANISM ; PULSE ANODIZATION ; HARD ANODIZATION ; NANOWIRE ARRAYS ; OXIDE ; FABRICATION ; MEMBRANES ; GROWTH ; FILMS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000311597200018 |
| 公开日期 | 2015-09-22 |
| 源URL | [http://ir.ia.ac.cn/handle/173211/8001]  |
| 专题 | 类脑智能研究中心_微观重建与智能分析 |
| 作者单位 | 1.Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Peoples R China 2.Chinese Acad Sci, Inst Automat, Natl Engn & Technol Res Ctr ASIC Design, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu Xu-Fei,Han Hua,Ma Hong-Tu,et al. Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina[J]. ACTA PHYSICO-CHIMICA SINICA,2012,28(11):2648-2658. |
| APA | Zhu Xu-Fei,Han Hua,Ma Hong-Tu,Lu Chao,Qi Wei-Xing,&Xu Chen.(2012).Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina.ACTA PHYSICO-CHIMICA SINICA,28(11),2648-2658. |
| MLA | Zhu Xu-Fei,et al."Influence of Reducer on the Nanopore Structure of Porous Anodic Alumina".ACTA PHYSICO-CHIMICA SINICA 28.11(2012):2648-2658. |
入库方式： OAI收割
来源：自动化研究所
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