Synthesis and photovoltaic properties of conjugated copolymers containing cyclopentadithiophene and two different electron-deficient moieties in the polymer backbone
文献类型：期刊论文
| 作者 | Li, Chao1; Li, Yongxi1; Wang, Xiaoyang2; Zhang, Bin3; Chen, Yu1 |
| 刊名 | journal of polymer research
 |
| 出版日期 | 2015-05-01 |
| 卷号 | 22期号:5 |
| 关键词 | Conjugated polymers Synthesis Thin films D-A(1)-D-A(2) copolymers |
| 英文摘要 | by using cyclopentadithiophene (cpdt) as an electron-rich unit, difluro-2,1,3-benzothiadiazole (dfbt), diketopyrrolopyrrole (dpp) and thienopyrroledione (tpd) as electron deficient units, two novel alternating conjugated copolymers with a d-a(1)-d-a(2) structure, pcpdt-dfbt-tpd and pcpdt-dfbt-dpp, were designed and synthesized. the incorporation of two electron-deficient units in the structure of terpolymer could enhance solubility, adjust band gap, optimize stack property, and change the electron distribution in the system. both the polymers pcpdt-dfbt-tpd and pcpdt-dfbt-dpp show highly solubility in o-dichlorobenzene, chlorobenzene, and o-xylene. optical bandgaps of these polymers can be estimated by extrapolating from the absorption edge of these films to be 1.56 ev for pcpdt-dfbt-tdp and 1.34 ev for pcpdt-dfbt-dpp. the power conversion efficiencies of 3.15 % for pcpdt-dfbt-tpd and 3.11 % for pcpdt-dfbt-dpp were achieved in a bulk heterojunction (bhj) photovoltaic device with a configuration of ito/pedot: pss/polymers: pc71bm/c-60-bis surfactant/ag under the illumination of am 1.5g at 100 ma cm(-2). |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | organic solar-cells ; acceptor copolymers ; performance ; absorption |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000354637800001 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/9085]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.E China Univ Sci & Technol, Inst Appl Chem, Key Lab Adv Mat, Shanghai 200237, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore |
| 推荐引用方式 GB/T 7714 | Li, Chao,Li, Yongxi,Wang, Xiaoyang,et al. Synthesis and photovoltaic properties of conjugated copolymers containing cyclopentadithiophene and two different electron-deficient moieties in the polymer backbone[J]. journal of polymer research,2015,22(5). |
| APA | Li, Chao,Li, Yongxi,Wang, Xiaoyang,Zhang, Bin,&Chen, Yu.(2015).Synthesis and photovoltaic properties of conjugated copolymers containing cyclopentadithiophene and two different electron-deficient moieties in the polymer backbone.journal of polymer research,22(5). |
| MLA | Li, Chao,et al."Synthesis and photovoltaic properties of conjugated copolymers containing cyclopentadithiophene and two different electron-deficient moieties in the polymer backbone".journal of polymer research 22.5(2015). |
入库方式： OAI收割
来源：广州能源研究所
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