Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)(3.5)[Al-4(PO4)(5)F]center dot 0.5H(3)O with extra-large 16-rings
文献类型：期刊论文
| 作者 | Zhang, Min; Zhou, Dan; Li, Jiyang; Yu, Jihong; Xu, Jun; Deng, Feng; Li, Guanghua; Xu, Ruren |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2007-01-08 |
| 卷号 | 46期号:1页码:136-140 |
| 英文摘要 | A new two-dimensional-layered fluoroaluminophosphate (C4H11NOH)(3.5)[Al-4(PO4)(5)F]center dot 0.5H(3)O (denoted as AlPO-CJ20) with an Al/P ratio of 4:5 has been synthesized solvothermally by using 2-amino-2-methyl-1-propanol as the structure-directing agent. Its structure was determined by single-crystal X-ray diffraction analysis and further characterized by solid-state NMR techniques, including Al-27, F-19 -> Al-27 cross-polarization, and P-31 magic angle spinning NMR. The alternation of Al-centered tetrahedra (AlO4 and AlO3F) and PO3(O) tetrahedra gives rise to a new type of 4.6.16-net sheet. The inorganic sheets are stacked in an ABAB sequence along the [010] direction and further held together through strong H bonds between protonated template molecules and PO groups in the inorganic layers. Except for Mu-4, AlPO-CJ20 is the second layered aluminophosphate with an Al/P ratio of 4:5, and it contains the largest pore opening of 16-rings in the known layered aluminophosphates. Furthermore, the coordination of Al and P of fluoroaluminophosphates is summarized. Crystal data: (C4H11NOH)(3.5)[Al-4(PO4)(5)F]center dot 0.5H(3)O, monoclinic, C2/c (No. 15), a = 32.678(7) angstrom, b = 12.956(3) angstrom, c = 21.045(4) angstrom, beta = 115.17(3)degrees, V = 8064(3) angstrom(3), Z = 8, R1 = 0.0837 [I > 2 sigma(I)], and wR2 = 0.2428 (all data). |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | OPEN-FRAMEWORK ALUMINOPHOSPHATE ; STATE NMR-SPECTROSCOPY ; CRYSTAL-STRUCTURE ; MOLECULAR-SIEVE ; ALUMINUM PHOSPHATE ; AL/P RATIO ; ALPO4-CHA ; FAMILY ; CHAIN ; IONS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000243157100018 |
| 公开日期 | 2015-10-13 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/7894]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Min,Zhou, Dan,Li, Jiyang,et al. Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)(3.5)[Al-4(PO4)(5)F]center dot 0.5H(3)O with extra-large 16-rings[J]. INORGANIC CHEMISTRY,2007,46(1):136-140. |
| APA | Zhang, Min.,Zhou, Dan.,Li, Jiyang.,Yu, Jihong.,Xu, Jun.,...&Xu, Ruren.(2007).Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)(3.5)[Al-4(PO4)(5)F]center dot 0.5H(3)O with extra-large 16-rings.INORGANIC CHEMISTRY,46(1),136-140. |
| MLA | Zhang, Min,et al."Synthesis and characterization of a new layered fluoroaluminophosphate (C4H11NOH)(3.5)[Al-4(PO4)(5)F]center dot 0.5H(3)O with extra-large 16-rings".INORGANIC CHEMISTRY 46.1(2007):136-140. |
入库方式： OAI收割
来源：武汉物理与数学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。