The reaction of molybdenum with 2,3-dihydroxynaphthalene
文献类型：期刊论文
| 作者 | Lu Xiao-Ming; Pei Xiu-Huan; Wang Xiao-Jun; Ye Chao-Hui |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2007-04-01 |
| 卷号 | 25期号:4页码:448-452 |
| 关键词 | 2 six-membered ring crystal structure enantiomer chiral pseudo-octahedral 3-dihydroxynaphthalene |
| 英文摘要 | [H2N(CH2)(3)NH3](2)[MoO2(C10H6O2)(2)] (1) was synthesized by the reaction of (n-Bu4N)(4)[Mo8O26] with 2,3-dihydroxynaphthalene in the mixed solvent of CH3OH, CH3CN and 1,3-propanediamine. (C5H11N2)(2)-[H2N(CH2)(3)NH2][MoO2(C10H6O2)(2)] (2) was obtained by the reaction of Na2MoO4-2H2O with 2,3-dihydroxynaphthalene in the same solvent above. Both of the complexes possess complex anion [Mo(VI)O-2(OC10H6O)(2)](2-) which shows pseudo-octahedrally coordinated fashion, while the counterions are two protonated 1,3-propanediamine in complex 1 and (C5H11N2)(+) in complex 2. (C5H11N2)(+) is the byproduct of reaction 2, which results from combination of acetonitrile with 1,3-propanediamine. Packing diagrarns of the two complexes are also different. There is anti-parallel-aligned-double-meso-bilayer unit in complex 1. However there are four chiral anions arranged in anticlockwise orientation in complex 2. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | OXYGEN-ATOM TRANSFER ; CRYSTAL-STRUCTURE ; TUNGSTEN COMPLEXES ; OLEFIN EPOXIDATION ; BIDENTATE LIGANDS ; OXO-TRANSFER ; EPR-SPECTRA ; CATALYSTS ; NMR ; CIS-DIOXO-MOLYBDENUM(V) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000245778200003 |
| 公开日期 | 2015-10-13 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/7910]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu Xiao-Ming,Pei Xiu-Huan,Wang Xiao-Jun,et al. The reaction of molybdenum with 2,3-dihydroxynaphthalene[J]. CHINESE JOURNAL OF CHEMISTRY,2007,25(4):448-452. |
| APA | Lu Xiao-Ming,Pei Xiu-Huan,Wang Xiao-Jun,&Ye Chao-Hui.(2007).The reaction of molybdenum with 2,3-dihydroxynaphthalene.CHINESE JOURNAL OF CHEMISTRY,25(4),448-452. |
| MLA | Lu Xiao-Ming,et al."The reaction of molybdenum with 2,3-dihydroxynaphthalene".CHINESE JOURNAL OF CHEMISTRY 25.4(2007):448-452. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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