中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The reaction of molybdenum with 2,3-dihydroxynaphthalene

文献类型:期刊论文

作者Lu Xiao-Ming; Pei Xiu-Huan; Wang Xiao-Jun; Ye Chao-Hui
刊名CHINESE JOURNAL OF CHEMISTRY
出版日期2007-04-01
卷号25期号:4页码:448-452
关键词2 six-membered ring crystal structure enantiomer chiral pseudo-octahedral 3-dihydroxynaphthalene
英文摘要[H2N(CH2)(3)NH3](2)[MoO2(C10H6O2)(2)] (1) was synthesized by the reaction of (n-Bu4N)(4)[Mo8O26] with 2,3-dihydroxynaphthalene in the mixed solvent of CH3OH, CH3CN and 1,3-propanediamine. (C5H11N2)(2)-[H2N(CH2)(3)NH2][MoO2(C10H6O2)(2)] (2) was obtained by the reaction of Na2MoO4-2H2O with 2,3-dihydroxynaphthalene in the same solvent above. Both of the complexes possess complex anion [Mo(VI)O-2(OC10H6O)(2)](2-) which shows pseudo-octahedrally coordinated fashion, while the counterions are two protonated 1,3-propanediamine in complex 1 and (C5H11N2)(+) in complex 2. (C5H11N2)(+) is the byproduct of reaction 2, which results from combination of acetonitrile with 1,3-propanediamine. Packing diagrarns of the two complexes are also different. There is anti-parallel-aligned-double-meso-bilayer unit in complex 1. However there are four chiral anions arranged in anticlockwise orientation in complex 2.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]OXYGEN-ATOM TRANSFER ; CRYSTAL-STRUCTURE ; TUNGSTEN COMPLEXES ; OLEFIN EPOXIDATION ; BIDENTATE LIGANDS ; OXO-TRANSFER ; EPR-SPECTRA ; CATALYSTS ; NMR ; CIS-DIOXO-MOLYBDENUM(V)
收录类别SCI
语种英语
WOS记录号WOS:000245778200003
公开日期2015-10-13
源URL[http://ir.wipm.ac.cn/handle/112942/7910]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China
2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China
推荐引用方式
GB/T 7714
Lu Xiao-Ming,Pei Xiu-Huan,Wang Xiao-Jun,et al. The reaction of molybdenum with 2,3-dihydroxynaphthalene[J]. CHINESE JOURNAL OF CHEMISTRY,2007,25(4):448-452.
APA Lu Xiao-Ming,Pei Xiu-Huan,Wang Xiao-Jun,&Ye Chao-Hui.(2007).The reaction of molybdenum with 2,3-dihydroxynaphthalene.CHINESE JOURNAL OF CHEMISTRY,25(4),448-452.
MLA Lu Xiao-Ming,et al."The reaction of molybdenum with 2,3-dihydroxynaphthalene".CHINESE JOURNAL OF CHEMISTRY 25.4(2007):448-452.

入库方式: OAI收割

来源:武汉物理与数学研究所

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