Solvothermal synthesis, structure and properties of two new compounds based on Keggin polyoxometalates decorated by copper complexes
文献类型：期刊论文
| 作者 | Wang, Xiaojun1; Lu, Xiaoming1; Li, Peizhou1; Pei, Xiuhuan1; Ye, Chaohui2 |
| 刊名 | JOURNAL OF COORDINATION CHEMISTRY
 |
| 出版日期 | 2008 |
| 卷号 | 61期号:23页码:3753-3762 |
| 关键词 | Polyoxometalates Organic-inorganic hybrid material Solvothermal synthesis One-dimensional chain Magnetic property |
| 英文摘要 | Two new organic-inorganic hybrid compounds based on polyoxometalate building blocks, [Cu(I)(bpy)(2)](2){[Cu(II)(bpy)](2)[PMo(3)(V)Mo(9)(VI)O(40)} (1), H[Cu(bpy)(H(2)O)]{[Cu(bpy)](4)(PO(4))(2)}{PW(11) CuO(39)} center dot H(2)O (2) (bpy = 2,2'-bipyridine), have been solvothermally synthesized and characterized by elemental analyses, IR, and TG analysis. Single crystal X-ray diffraction reveals that 1 is built from the reduced alpha-Keggin polyoxoanion [PMo(3)(V)Mo(9)(VI)O(40)](6-) bicapped by two [Cu(II)(bpy)](2+) through four bridging oxo groups on two opposite [Mo(4)O(4)] faces. 1 shows mild photoluminescence in the solid state at room temperature. 2 is based on monovacant Keggin anion {PW(11)CuO(39)}(5-) linked through Cu(bpy)(2+) andPO(4)(3-), generating a one-dimensional chain. Magnetism indicates predominantly antiferromagnetic interaction in 2. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Inorganic & Nuclear |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HYDROTHERMAL SYNTHESIS ; BUILDING-BLOCKS ; COORDINATION-COMPLEXES ; CRYSTAL-STRUCTURE ; IONIC-CRYSTAL ; CLUSTERS ; POLYMER ; OXIDE ; CHAINS ; NETWORKS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000260213200004 |
| 公开日期 | 2015-10-13 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8037]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Xiaojun,Lu, Xiaoming,Li, Peizhou,et al. Solvothermal synthesis, structure and properties of two new compounds based on Keggin polyoxometalates decorated by copper complexes[J]. JOURNAL OF COORDINATION CHEMISTRY,2008,61(23):3753-3762. |
| APA | Wang, Xiaojun,Lu, Xiaoming,Li, Peizhou,Pei, Xiuhuan,&Ye, Chaohui.(2008).Solvothermal synthesis, structure and properties of two new compounds based on Keggin polyoxometalates decorated by copper complexes.JOURNAL OF COORDINATION CHEMISTRY,61(23),3753-3762. |
| MLA | Wang, Xiaojun,et al."Solvothermal synthesis, structure and properties of two new compounds based on Keggin polyoxometalates decorated by copper complexes".JOURNAL OF COORDINATION CHEMISTRY 61.23(2008):3753-3762. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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