Helical nanostructure of tubular metal-organic complex synthesized by sonochemical process
文献类型：期刊论文
| 作者 | Wang Ting1; Lu XiaoMing1; Han Li1; Pang XiaoLi1; Ye ChaoHui2 |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2008-10-01 |
| 卷号 | 51期号:10页码:971-975 |
| 关键词 | metal-organic complex helical nanostructure sonochemical method |
| 英文摘要 | Tubular metal-organic complex (C(2)H(9)N(2))(2)(C(2)H(10)N(2))(0.5)[MoO(2)(OC(6)H(4)O)(2)] has been synthesized. The title complex crystallizes in the tetragonal system, space group P4(2)/n with a = 25.214(8), c = 7.484(4) angstrom, and Z = 8. The X- ray structural analysis of the complex reveals tube-like framework which is stabilized by hydrogen bond. Chiral anions [Mo((V))O(2)(OC(6)H(4)O)(2)](3-) of the complex have two types of isomers(lambda/delta configuration). Helical nanostructure of this metal-organic complex was formed using a sonochemical method. Sonocation may lead to the transformation from the bulk tubular complex to the helical nanostructure. The as-synthesized nanohelices were all double-stranded and left-and right-handed nanohelices were both formed. The helical nanostructure is a new morphology of inorganic-organic hybrid materials on the nanoscale level and the exact formation mechanism of these helices still needs further investigation. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | CRYSTAL-STRUCTURE ; NANOTUBES ; EPR ; MECHANISM |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259258500008 |
| 公开日期 | 2015-10-13 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/8089]  |
| 专题 | 武汉物理与数学研究所_2011年以前论文发表（包括2011年） |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Ting,Lu XiaoMing,Han Li,et al. Helical nanostructure of tubular metal-organic complex synthesized by sonochemical process[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2008,51(10):971-975. |
| APA | Wang Ting,Lu XiaoMing,Han Li,Pang XiaoLi,&Ye ChaoHui.(2008).Helical nanostructure of tubular metal-organic complex synthesized by sonochemical process.SCIENCE IN CHINA SERIES B-CHEMISTRY,51(10),971-975. |
| MLA | Wang Ting,et al."Helical nanostructure of tubular metal-organic complex synthesized by sonochemical process".SCIENCE IN CHINA SERIES B-CHEMISTRY 51.10(2008):971-975. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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