Photodissociation study of 1,2-C(2)H(4)BrCl at 234 and 267 nm by the ion-velocity imaging technique
文献类型:期刊论文
作者 | Hua, Linqiang; Shen, Huan; Zhang, Changhua; Cao, Zhenzhou; Zhang, Bing1 |
刊名 | CHEMICAL PHYSICS LETTERS
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出版日期 | 2008-07-20 |
卷号 | 460期号:1-3页码:50-54 |
英文摘要 | The photodissociation of 1,2-C(2)H(4)BrCl has been investigated at 234 and 267 nm using the ion-velocity imaging technique. The images of the bromine fragments show the characteristics of a direct dissociation process and the extracted anisotropy parameters indicate the molecules are mainly excited to (3)Q(0) state at both wavelength. A new decomposition channel on the ground state was observed. It was attributed to internal conversion from the excited electronic state to the ground state. The product quantum yields were measured to be Phi(234nm)(Br*) = 0.39 and Phi(267nm)(Br*) = 0.25, and the contribution of each state to the product was estimated. (C) 2008 Elsevier B. V. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
研究领域[WOS] | Chemistry ; Physics |
关键词[WOS] | ATMOSPHERIC BROMINE ; METHYL-IODIDE ; IONIZATION ; DYNAMICS ; CH2BRCL |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000257596300011 |
公开日期 | 2015-10-20 |
源URL | [http://ir.wipm.ac.cn/handle/112942/8122] ![]() |
专题 | 武汉物理与数学研究所_2011年以前论文发表(包括2011年) |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Hua, Linqiang,Shen, Huan,Zhang, Changhua,et al. Photodissociation study of 1,2-C(2)H(4)BrCl at 234 and 267 nm by the ion-velocity imaging technique[J]. CHEMICAL PHYSICS LETTERS,2008,460(1-3):50-54. |
APA | Hua, Linqiang,Shen, Huan,Zhang, Changhua,Cao, Zhenzhou,&Zhang, Bing.(2008).Photodissociation study of 1,2-C(2)H(4)BrCl at 234 and 267 nm by the ion-velocity imaging technique.CHEMICAL PHYSICS LETTERS,460(1-3),50-54. |
MLA | Hua, Linqiang,et al."Photodissociation study of 1,2-C(2)H(4)BrCl at 234 and 267 nm by the ion-velocity imaging technique".CHEMICAL PHYSICS LETTERS 460.1-3(2008):50-54. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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