Furthering the chemosensing of silver nanoclusters for ion detection
文献类型：期刊论文
| 作者 | Ding, Weihua1,2; Huang, Saipeng1,2; Guan, Lingmei1,2; Liu, Xianhu1,2; Luo, Zhixun1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:79页码:64138-64145 |
| 英文摘要 | Ligand-protected metal nanoclusters (NCs) having hydrodynamic diameters and fluorescent properties have reasonable potential for ion detection and bio-imaging applications by taking advantage of their smaller sizes and degradability as compared with larger nanoparticles. By controlling the pH value, here we have synthesized a fluorescent silver nanocluster, Ag-glutathione, which is found to be a versatile chemosensor operative for the detection of both manganese (Mn2+) and iodine (I-) ions. Mn2+ and I- are further distinguished by the ratiometric absorption spectrometry method. Care was taken for sufficient spectral analyses, based upon which we have fully demonstrated the chemosensing mechanisms of Ag@glutathione (Ag@SG) NCs applied in ion detection. Having expounded this issue, we further investigated the potential application of Ag@SG NCs in bio-imaging. It is interesting to find that the as-prepared Ag@SG NCs are nontoxic and available for fluorescence imaging of MCF-7 cells, with on/off alternation of fluorescence emission in the presence of Mn2+ or I- ions. The low cytotoxicity, good penetrability and on/off fluorescence property of Ag@SG NCs in MCF-7 cells suggest promising biological applications. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27798]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.GUCAS, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Weihua,Huang, Saipeng,Guan, Lingmei,et al. Furthering the chemosensing of silver nanoclusters for ion detection[J]. RSC ADVANCES,2015,5(79):64138-64145. |
| APA | Ding, Weihua,Huang, Saipeng,Guan, Lingmei,Liu, Xianhu,&Luo, Zhixun.(2015).Furthering the chemosensing of silver nanoclusters for ion detection.RSC ADVANCES,5(79),64138-64145. |
| MLA | Ding, Weihua,et al."Furthering the chemosensing of silver nanoclusters for ion detection".RSC ADVANCES 5.79(2015):64138-64145. |
入库方式： OAI收割
来源：化学研究所
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