Homomeric Inclusion and Hydrogen-Bonding Cooperatively Directed Crystalline Assembly of a Cyclotriguaiacylene Derivative with Different Aromatic Acids
文献类型：期刊论文
| 作者 | Song, Jingru; Shi, Yanyan; Huang, Zhitang; Zheng, Qiyu |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2015-07-01 |
| 卷号 | 33期号:7页码:765-770 |
| 关键词 | cyclotriveratrylene hydrogen bonds C-H center dot center dot center dot pi interactions inclusion compounds crystal engineering |
| 英文摘要 | Five organic complexes are prepared by cocrystallization of tri-[(N-methyl-2-imidazoly)methoxy]cyclotriguiacylene (TMIM-CTG) with corresponding acids. While hydrogen bonds are the basic interactions in the five complexes, the homo-included motifs with C-H center dot center dot center dot pi interactions also control the molecular arrangement except for complex 5. In complex 1, the two dimensional networks contain 1D zigzag chains formed by hydrogen bonding and 1D chains of homo-included CTG motifs. Complex 2 has 2D 4 center dot 8(2) hydrogen bonding networks, and the chains of homomeric inclusion extend the 2D structure to a 3D framework. Complex 3 contains four-membered rings through hydrogen bonds, and the chains of homo-inclusion link the rings to a novel 2D network. In complex 4, hydrogen bonds construct a novel double-layer 2D network, which is extended to a 3D framework by "hand-shake" dimeric homomeric inclusion interactions. Interestingly, there is no homomeric inclusion phenomenon in complex 5 and hydrogen bonds solely connect two components to a chiral (6,3) 2D network. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27853]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jingru,Shi, Yanyan,Huang, Zhitang,et al. Homomeric Inclusion and Hydrogen-Bonding Cooperatively Directed Crystalline Assembly of a Cyclotriguaiacylene Derivative with Different Aromatic Acids[J]. CHINESE JOURNAL OF CHEMISTRY,2015,33(7):765-770. |
| APA | Song, Jingru,Shi, Yanyan,Huang, Zhitang,&Zheng, Qiyu.(2015).Homomeric Inclusion and Hydrogen-Bonding Cooperatively Directed Crystalline Assembly of a Cyclotriguaiacylene Derivative with Different Aromatic Acids.CHINESE JOURNAL OF CHEMISTRY,33(7),765-770. |
| MLA | Song, Jingru,et al."Homomeric Inclusion and Hydrogen-Bonding Cooperatively Directed Crystalline Assembly of a Cyclotriguaiacylene Derivative with Different Aromatic Acids".CHINESE JOURNAL OF CHEMISTRY 33.7(2015):765-770. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。