Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes
文献类型：期刊论文
| 作者 | Mou, Zehuai1,2; Xie, Hongyan1,2; Wang, Meiyan3; Liu, Na1,2; Yao, Changguang1,2; Li, Lei1,2; Liu, Jingyao3; Li, Shihui1; Cui, Dongmei1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2015-08-24 |
| 卷号 | 34期号:16页码:3944-3949 |
| 英文摘要 | Treatment of heteroscorpionate zinc benzyloxy complex LZnOBn (1, L = ((Me)Pz)(2)CP(Ph)(2)NPh, (Me)Pz = 3,5-dimethylpyrazolyl) with phenylsilane (PhSiH3) gave a zinc hydride complex LZnH (2) containing a rare terminal hydride fragment. X-ray diffraction analysis and the DFT calculation confirm the zwitterionic structure of complex 2. The stoichiometric reaction of 2 with CS2 readily afforded a dithioformate complex LZnSCH(S) (3) of the C=S insertion into the Zn-H product. Moreover, complex 2 was an efficient catalyst for the hydrosilylation reaction of a series of silanes and aldehydes under mild conditions, featuring excellent functional group tolerance. The preliminary mechanistic study revealed that both zinc benzyloxy complex 1 and zinc hydride complex 2 were involved in the hydrosilylation process as the reaction intermediates. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27700]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Changchun Branch, Changchun 130022, Peoples R China 3.Jilin Univ, Inst Theoret Chem, State Key Lab Theoret & Computat Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mou, Zehuai,Xie, Hongyan,Wang, Meiyan,et al. Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes[J]. ORGANOMETALLICS,2015,34(16):3944-3949. |
| APA | Mou, Zehuai.,Xie, Hongyan.,Wang, Meiyan.,Liu, Na.,Yao, Changguang.,...&Cui, Dongmei.(2015).Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes.ORGANOMETALLICS,34(16),3944-3949. |
| MLA | Mou, Zehuai,et al."Mononuclear Heteroscorpionate Zwitterionic Zinc Terminal Hydride: Synthesis, Reactivity, and Catalysis for Hydrosilylation of Aldehydes".ORGANOMETALLICS 34.16(2015):3944-3949. |
入库方式： OAI收割
来源：化学研究所
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