A porous metal-organic framework formed by a V-shaped ligand and Zn(II) ion with highly selective sensing for nitroaromatic explosives
文献类型：期刊论文
| 作者 | He, Hongming1; Song, Yang1; Sun, Fuxing1; Bian, Zheng2; Gao, Lianxun2; Zhu, Guangshan1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2015 |
| 卷号 | 3期号:32页码:16598-16603 |
| 英文摘要 | A V-shaped aromatic ligand 1,3-di(4-carboxyphenyl)benzene (H2DCPB), retaining only one branch of the H6TDCPB ligand, was utilized. The assembly of this ligand with Zn(II) ions forms a two-fold interpenetrated porous MOF with pcu topology (JUC-135). The N-2 adsorption isotherm of the activated sample at 77 K revealed type-I microporous characteristics. The BET and Langmuir surface areas are calculated to be 503.7 m(2) g(-1) and 718.9 m(2) g(-1), respectively. Notably, by the fluorescence technique, JUC-135 can be used to detect nitroaromatic explosives. In particular, it is one of the most efficient porous material-based sensors for TNP(K-SV = 3.7 x 10(4) M-1). Furthermore, JUC-135 also can distinguish TNP (blue-shift) from NB, 1,3-DNB and 2,4-DNT (red-shift) by virtue of the shift direction of fluorescence spectra. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27744]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Hongming,Song, Yang,Sun, Fuxing,et al. A porous metal-organic framework formed by a V-shaped ligand and Zn(II) ion with highly selective sensing for nitroaromatic explosives[J]. JOURNAL OF MATERIALS CHEMISTRY A,2015,3(32):16598-16603. |
| APA | He, Hongming,Song, Yang,Sun, Fuxing,Bian, Zheng,Gao, Lianxun,&Zhu, Guangshan.(2015).A porous metal-organic framework formed by a V-shaped ligand and Zn(II) ion with highly selective sensing for nitroaromatic explosives.JOURNAL OF MATERIALS CHEMISTRY A,3(32),16598-16603. |
| MLA | He, Hongming,et al."A porous metal-organic framework formed by a V-shaped ligand and Zn(II) ion with highly selective sensing for nitroaromatic explosives".JOURNAL OF MATERIALS CHEMISTRY A 3.32(2015):16598-16603. |
入库方式： OAI收割
来源：化学研究所
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