Donor-acceptor-donor conjugated oligomers based on isoindigo and anthra[1,2-b]thieno[2,3-d]thiophene for organic thin-film transistors: the effect of the alkyl side chain length on semiconducting properties
文献类型：期刊论文
| 作者 | Shao, Jing1,2; Zhang, Xiaojie1; Tian, Hongkun1; Geng, Yanhou1; Wang, Fosong1 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY C
 |
| 出版日期 | 2015 |
| 卷号 | 3期号:29页码:7567-7574 |
| 英文摘要 | Three donor-acceptor-donor (D-A-D) conjugated oligomers, i.e., 2ATT-IID-C8C10, 2ATT-IID-C6C8 and 2ATT-IID-C4C6, have been synthesized using anthra[1,2-b]thieno[2,3-d]thiophene (ATT) as an electron-donor unit and isoindigo (IID) as an electron-acceptor unit by combining the planar and rigid structure of fused aromatics and the strong intramolecular interaction of D-A conjugated molecules, and their semiconducting properties were studied via organic thin-film transistors (OTFTs). The alkyl chains, which are 2-octyldodecyl (C8C10), 2-hexyldecyl (C6C8) and 2-butyloctyl (C4C6), respectively, were employed in the IID unit in order to study the effect of alkyl bulkiness on the properties of the oligomers. All three oligomers adopted an edge-on alignment in thin films. Decreasing the bulkiness or length of the alkyls caused a noticeable improvement of the packing order of the oligomers, leading to a remarkably enhanced charge carrier mobility. 2ATT-IID-C8C10 could only form the film featured with one-dimensional order. Consequently, it exhibited the lowest OTFT mobility (<0.1 cm(2) V-1 s(-1)). In contrast, both 2ATT-IID-C6C8 and 2ATT-IID-C4C6 adopted two-dimensional-ordered packing structures after thermal annealing with a pi-pi stacking distance of similar to 3.6 angstrom, thereby exhibiting promising semiconducting properties. 2ATT-IID-C4C6 showed the best OTFT performance with a mobility of 0.72 cm(2) V-1 s(-1). This mobility is among the highest for the solution processible D-A conjugated oligomers to date. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27871]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, Jing,Zhang, Xiaojie,Tian, Hongkun,et al. Donor-acceptor-donor conjugated oligomers based on isoindigo and anthra[1,2-b]thieno[2,3-d]thiophene for organic thin-film transistors: the effect of the alkyl side chain length on semiconducting properties[J]. JOURNAL OF MATERIALS CHEMISTRY C,2015,3(29):7567-7574. |
| APA | Shao, Jing,Zhang, Xiaojie,Tian, Hongkun,Geng, Yanhou,&Wang, Fosong.(2015).Donor-acceptor-donor conjugated oligomers based on isoindigo and anthra[1,2-b]thieno[2,3-d]thiophene for organic thin-film transistors: the effect of the alkyl side chain length on semiconducting properties.JOURNAL OF MATERIALS CHEMISTRY C,3(29),7567-7574. |
| MLA | Shao, Jing,et al."Donor-acceptor-donor conjugated oligomers based on isoindigo and anthra[1,2-b]thieno[2,3-d]thiophene for organic thin-film transistors: the effect of the alkyl side chain length on semiconducting properties".JOURNAL OF MATERIALS CHEMISTRY C 3.29(2015):7567-7574. |
入库方式： OAI收割
来源：化学研究所
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