Facile Fabrication of Fast Recyclable and Multiple Self-healing Epoxy Materials through Diels-Alder Adduct Cross-linker
文献类型：期刊论文
| 作者 | Kuang, Xiao1; Liu, Guoming1; Dong, Xia1; Liu, Xianggui1; Xu, Jianjun2; Wang, Dujin1 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2015-09-15 |
| 卷号 | 53期号:18页码:2094-2103 |
| 关键词 | adduct crosslinker adhesives Diels-Alder polymers epoxy resin recycling self-healing thermosets |
| 英文摘要 | A reversibly cross-linked epoxy resin with efficient reprocessing and intrinsic self-healing was prepared from a diamine Diels-Alder (DA) adduct cross-linker and a commercial epoxy oligomer. The newly synthesized diamine cross-linker, comprising a DA adduct of furan and maleimide moieties, can cure epoxy monomer/oligomer with thermal reversibility. The reversible transition between cross-linked state and linear architecture endows the cured epoxy with rapid recyclability and repeated healability. The reversibly cross-linked epoxy fundamentally behaves as typical thermosets at ambient conditions yet can be fast reprocessed at elevated temperature like thermoplastics. As a potential reversible adhesive, the epoxy polymer with adhesive strength values about 3 MPa showed full recovery after repeated fracture-thermal healing processes. The methodology explored in this contribution provides new insights in modification of conventional engineering plastics as functional materials. (C) 2015 Wiley Periodicals, Inc. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27785]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.DSM Resolve, NL-6160 MD Geleen, Netherlands |
| 推荐引用方式 GB/T 7714 | Kuang, Xiao,Liu, Guoming,Dong, Xia,et al. Facile Fabrication of Fast Recyclable and Multiple Self-healing Epoxy Materials through Diels-Alder Adduct Cross-linker[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2015,53(18):2094-2103. |
| APA | Kuang, Xiao,Liu, Guoming,Dong, Xia,Liu, Xianggui,Xu, Jianjun,&Wang, Dujin.(2015).Facile Fabrication of Fast Recyclable and Multiple Self-healing Epoxy Materials through Diels-Alder Adduct Cross-linker.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,53(18),2094-2103. |
| MLA | Kuang, Xiao,et al."Facile Fabrication of Fast Recyclable and Multiple Self-healing Epoxy Materials through Diels-Alder Adduct Cross-linker".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 53.18(2015):2094-2103. |
入库方式： OAI收割
来源：化学研究所
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