Ethylene polymerization by the thermally unique 1-[2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino]-2-aryliminoacenaphthylnickel precursors
文献类型：期刊论文
| 作者 | Du, Shizhen1,2; Xing, Qifeng1,2; Flisak, Zygmunt1,2; Yue, Erlin1,2; Sun, Yang1,2; Sun, Wen-Hua1,2,3
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| 刊名 | DALTON TRANSACTIONS
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| 出版日期 | 2015 |
| 卷号 | 44期号:27页码:12282-12291 |
| 英文摘要 | A series of 1-[2-(bis(4-fluorophenyl)methyl)-4,6-dimethylphenylimino]-2-aryliminoacenaphthylene derivatives together with the corresponding nickel bromide complexes was synthesized and characterized. Representative complexes C2 and C5 were characterized by the single-crystal X-ray diffraction, revealing a distorted tetrahedral geometry. Upon activation with either methylaluminoxane (MAO) or ethylaluminum sesquichloride (EASC), all nickel complexes exhibited high activities towards ethylene polymerization, producing polyethylene with a relatively low degree of branching and narrow polydispersity. Complex C1 maintained good activity at elevated reaction temperatures, which indicates significant thermal stability of the active species. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/27815]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Shizhen,Xing, Qifeng,Flisak, Zygmunt,et al. Ethylene polymerization by the thermally unique 1-[2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino]-2-aryliminoacenaphthylnickel precursors[J]. DALTON TRANSACTIONS,2015,44(27):12282-12291. |
| APA | Du, Shizhen,Xing, Qifeng,Flisak, Zygmunt,Yue, Erlin,Sun, Yang,&Sun, Wen-Hua.(2015).Ethylene polymerization by the thermally unique 1-[2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino]-2-aryliminoacenaphthylnickel precursors.DALTON TRANSACTIONS,44(27),12282-12291. |
| MLA | Du, Shizhen,et al."Ethylene polymerization by the thermally unique 1-[2-(bis(4-fluoro phenyl)methyl)-4,6-dimethylphenylimino]-2-aryliminoacenaphthylnickel precursors".DALTON TRANSACTIONS 44.27(2015):12282-12291. |
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来源：化学研究所
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