Rational Assembly of Co/Cd-MOFs Featuring Topological Variation
文献类型：期刊论文
| 作者 | Wang, Hao ; Yi, Fei-Yan ; Dang, Song ; Tian,Wan-Guo ; Sun,Zhong-Ming |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2014 |
| 卷号 | 14期号:1页码:147-156 |
| 关键词 | METAL-ORGANIC FRAMEWORKS AROMATIC POLYCARBOXYLATE ACIDS PHOTO LUMINESCENT PROPERTIES N-DONOR LIGANDS COORDINATION POLYMERS MAGNETIC-PROPERTIES CRYSTAL-STRUCTURES HYDROGEN STORAGE SMALL MOLECULES DRUG-DELIVERY |
| 通讯作者 | sun,zm |
| 英文摘要 | three different carboxylate ligands of 4,4'-biphthalic acid (h4l, linear), 4,4'-axydiphthalic acid (h4lo, v-shaped), and thiophene-2,5-dicarboxylic acid (h2ls, v-shaped and heteroatomic ring) were selected as two-connected nodes to react with co(ii) or cd(ii) nitrates in the presence of 1,3,5-tris(1-imidazolyl)benzene (fib, y-shaped and tridentate). hydrothermal reactions in distilled water afforded seven new co(cd)-mofs, namely, m(tib)(h2l)center dot(h2o)(2)center dot h2o (m = co, 1; cd, 2), m-2 (tib)(2)(h2lo)(2)(h2o)(2) (m co, 3; cd, 4), co-2(tib)(l-o)center dot h2o (5), co(tib)(l-s)center dot 2h(2)o (6), and cd(tib)(l-s)center dot 3h(2)o (7). of particular interest, they exhibit four interesting nets. 1-2 and 3-4 feature binodal (3,4) and (3,3,4,4)-connected nets if h-bonds are taken into account, respectively. 5 is composed of a two-dimensional metal-l layer and a one-dimensional metal-tib chain and simplified into a 4-nodal (3,4,4,5)-connected net. 6 and 7 feature rare binodal (3,5)-connected {3.7(2)}{3(2).7(5).8(3)} fsf/polar net and (3,5)-connected {6(3)}{6(9).8} hms net. structural analyses show that each type of compound with the same metal components and fib ligands exhibit such interesting topological variations, which are derived from different orientations of three carboxylate ligands. other properties of these compounds were also investigated, such as elemental and thermogravimetric analyses, photoluminescent spectroscopy, and magnetic behavior. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/56178]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang, Hao,Yi, Fei-Yan,Dang, Song,et al. Rational Assembly of Co/Cd-MOFs Featuring Topological Variation[J]. crystal growth & design,2014,14(1):147-156. |
| APA | Wang, Hao,Yi, Fei-Yan,Dang, Song,Tian,Wan-Guo,&Sun,Zhong-Ming.(2014).Rational Assembly of Co/Cd-MOFs Featuring Topological Variation.crystal growth & design,14(1),147-156. |
| MLA | Wang, Hao,et al."Rational Assembly of Co/Cd-MOFs Featuring Topological Variation".crystal growth & design 14.1(2014):147-156. |
入库方式： OAI收割
来源：长春应用化学研究所
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