Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers
文献类型:期刊论文
作者 | Yang, Weiting ; Tian, Wan-Guo ; Liu, Xiao-Xiao ; Wang,Lei ; Sun,Zhong-Ming |
刊名 | crystal growth & design
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出版日期 | 2014 |
卷号 | 14期号:11页码:5904-5911 |
关键词 | METAL-ORGANIC FRAMEWORKS CATION-CATION INTERACTION BOND-VALENCE PARAMETERS CRYSTAL-STRUCTURES RHODAMINE-B EXTENDED STRUCTURES URANIUM GERMANATE ION-EXCHANGE LIGANDS DIPHOSPHONATES |
通讯作者 | sun,zm |
英文摘要 | a new series of uranium coordination polymers have been hydrothermally synthesized by using 4,4'-oxidiphthalic acid (h4l) in the presence of n-bearing species, namely, (h(2)dpa)uo2l.3h(2)o (1), (h(2)dib)uo2l.h2o (2), (h(2)bbi)(uo2)l.3h(2)o (3), (h(2)dib)(dib)(0.5)[uo2l(dib)].3h(2)o (4), (h(2)bbi)(u2o5)l.2h(2)o (5), and (hbpi)(2)(uo(2)f())2l (6) [dpa = di(pyridin-4-yl)amine, dib = 1,4-di(1h-imidazol-1-yl)benzene, bbi = 1,1'-(1,4-butanediyl)bis(imidazole), and bpi = 1-(biphenyl-4-yl)-1h-imidazole]. compounds 13 exhibit the ribbon structures with dpa, dib, and bbi as the templates, respectively. compound 4 represents a one-dimensional chain assembly of uranyl centers, l ligands, and coordinated dib molecules. compound 5 contains the tetranuclear motifs of edge-sharing of two uo7 pentagonal and two uo8 hexagonal bipyramids, which are linked by l ligands forming a layered structure with bbi as the template. compound 6 forms a two-dimensional arrangement, in which the chain structures of edge-sharing uo5f2 pentagonal bipyramids are pillared by l ligands. luminescence studies reveal the characterized green light emission from uranyl centers for these uranyl carboxylates. moreover, the excellent visible light photodegradation activities for rhb are displayed by these coordination polymers. |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
源URL | [http://ir.ciac.jl.cn/handle/322003/56183] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Yang, Weiting,Tian, Wan-Guo,Liu, Xiao-Xiao,et al. Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers[J]. crystal growth & design,2014,14(11):5904-5911. |
APA | Yang, Weiting,Tian, Wan-Guo,Liu, Xiao-Xiao,Wang,Lei,&Sun,Zhong-Ming.(2014).Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers.crystal growth & design,14(11),5904-5911. |
MLA | Yang, Weiting,et al."Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers".crystal growth & design 14.11(2014):5904-5911. |
入库方式: OAI收割
来源:长春应用化学研究所
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