Design, Synthesis, and Optoelectronic Properties of Dendrimeric Pt(II) Complexes and Their Ability to Inhibit Intermolecular Interaction
文献类型：期刊论文
| 作者 | Li, Hui ; Li, Jing ; Ding, Junqiao ; Yuan,Wei ; Zhang,Zilong ; Zou,Luyi ; Wang,Xingdong ; Zhan,Hongmei ; Xie,Zhiyuan ; Cheng,Yanxiang |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 53期号:2页码:810-821 |
| 关键词 | LIGHT-EMITTING-DIODES CYCLOMETALATED PLATINUM(II) COMPLEXES EFFECTIVE CORE POTENTIALS EXTERNAL QUANTUM EFFICIENCY ELECTROLUMINESCENT DEVICES ELECTROPHOSPHORESCENT PROPERTIES PHOTOPHYSICAL PROPERTIES MOLECULAR CALCULATIONS PHOSPHORESCENT MATERIALS LIGANDS |
| 通讯作者 | zhan,hm |
| 英文摘要 | dendrimeric pt(ii) complexes [((cn)-n-boolean and)pt(dpm)] and [pt((cn)-n-boolean and)(2)] (hdpm = dipivaloylmethane, (hcn)-n-boolean and = 1,2-diphenylbenzoimidazole and its derivatives containing the carbazole. dendrons) have been synthesized and characterized systematically. all of the complexes display green emission in the range of 495-535 nm that originated from the 360-440 nm absorption bands, which are assigned to d pi(pt)->pi*(l) metal-to-ligand charge transfer (mlct) mixed with intraligand pi(l)->pi*(l) transition. solution photoluminescence quantum yield (phi(p) 0.26-0.31) of the heteroleptic complexes [((cn)-n-boolean and)pt(dpm)] obviously increases when compared with that of complex [((cn)-n-boolean and)pt(acac)]. organic light-emitting diode devices based on these pt(ii) complexes with a multilayer configuration were fabricated and gave desirable electroluminescent (el) performances, such as non- or less red-shifted el spectra, in comparison with the photoluminescence spectra and slow efficiency roll-off with increasing brightness or current density. complex [(t-buczczpbi)pt(dpm)] (where t-buczczpbi = 1-(4-(3,6-di-(3,6-di-t-butylcarbazol-9-yl))carbazol-9-yl)phenyl-2-phenylbenzoimidazole) showed the best performance, with a maximum current efficiency of 29.31 cd/a and a maximum external quantum efficiency (eqe) of 9.04% among the fabricated devices. likewise, for homoleptic [pt(t-buczczpbi)(2)] dendrimer, the powder phi(p) (0.14) and maximum eqe (0.74%) improve by 7 and 7.4 times, respectively, as high as they do for nondendrimeric [pt(1,2-diphenylbenzoimidazole)(2)] (0.02, 0.10%), although its efficiency is still lower than that of the heteroleptic counterpart due to the severely distorted square-planar geometry of the emitting core. these results reveal that large steric hindrance from ancillary ligand (dpm) or the homoleptic conformation can effectively inhibit intermolecular interaction for these denchimeric pt(ii) complexes. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2015-10-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/56199]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li, Hui,Li, Jing,Ding, Junqiao,et al. Design, Synthesis, and Optoelectronic Properties of Dendrimeric Pt(II) Complexes and Their Ability to Inhibit Intermolecular Interaction[J]. inorganic chemistry,2014,53(2):810-821. |
| APA | Li, Hui.,Li, Jing.,Ding, Junqiao.,Yuan,Wei.,Zhang,Zilong.,...&Cheng,Yanxiang.(2014).Design, Synthesis, and Optoelectronic Properties of Dendrimeric Pt(II) Complexes and Their Ability to Inhibit Intermolecular Interaction.inorganic chemistry,53(2),810-821. |
| MLA | Li, Hui,et al."Design, Synthesis, and Optoelectronic Properties of Dendrimeric Pt(II) Complexes and Their Ability to Inhibit Intermolecular Interaction".inorganic chemistry 53.2(2014):810-821. |
入库方式： OAI收割
来源：长春应用化学研究所
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