Molecular Magnetic Investigation of a Family of Octanuclear [Cu(6)Ln(2)] Nanoclusters
文献类型：期刊论文
| 作者 | Xue,Shufang ; Guo,Yun-Nan ; Zhao,Lang ; Zhang,Haixia ; Tang,Jinkui |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2014 |
| 卷号 | 53期号:15页码:8165-8171 |
| 关键词 | SOFT ACIDS COMPLEXES CLUSTERS EXCHANGE LIGANDS REFRIGERANTS BLOCKING BEHAVIOR BASES HARD |
| 通讯作者 | tang,jk |
| 英文摘要 | reaction of in situ prepared acylhydrazone ligand with ln(no3)(3)center dot 6h(2)o and cu(oac)(2)center dot h2o resulted in the formation of novel isostructural octanuclear cu(6)ln(2) compounds (ln = dy (1), tb (2), gd (3), y (4)) with an unprecedented octametallic structure, which can be described as an oblate wheel built up from two structurally similar cu-3 fragments linked together by two nodelike mononuclear lanthanide units. a detailed magnetic analysis reveals that the strong antiferromagnetic cu center dot center dot center dot cu interactions via the cu-n- n-cu-n-n-cu linkage and the anticipated ferromagnetic cu center dot center dot center dot gd coupling makes an overall high-spin ground state in favor of the observation of significant magnetic caloric and smm-like properties in the isotropic and anisotropic derivatives. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000339982400046 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/56206]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Xue,Shufang,Guo,Yun-Nan,Zhao,Lang,et al. Molecular Magnetic Investigation of a Family of Octanuclear [Cu(6)Ln(2)] Nanoclusters[J]. inorganic chemistry,2014,53(15):8165-8171. |
| APA | Xue,Shufang,Guo,Yun-Nan,Zhao,Lang,Zhang,Haixia,&Tang,Jinkui.(2014).Molecular Magnetic Investigation of a Family of Octanuclear [Cu(6)Ln(2)] Nanoclusters.inorganic chemistry,53(15),8165-8171. |
| MLA | Xue,Shufang,et al."Molecular Magnetic Investigation of a Family of Octanuclear [Cu(6)Ln(2)] Nanoclusters".inorganic chemistry 53.15(2014):8165-8171. |
入库方式： OAI收割
来源：长春应用化学研究所
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