Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment
文献类型:期刊论文
作者 | Xue,Shufang ; Ungur,L ; Guo,Yun-Nan ; Tang,Jinkui ; Chibotaru,Liviu F. |
刊名 | inorganic chemistry
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出版日期 | 2014 |
卷号 | 53期号:23页码:12658-12663 |
关键词 | SINGLE-MOLECULE MAGNETS POLYHEDRAL STRUCTURES ANISOTROPY BARRIER ODD NUMBER COMPLEXES BEHAVIOR SUBSTITUTION AGGREGATE CHEMISTRY BLOCKING |
通讯作者 | ungur,l |
英文摘要 | a defective cubane-shaped heterometallic trinuclear (co2dyiii)-dy-iii compound with only one magnetically interesting ion (dy-iii) has been assembled by virtue of a multifunctional acylhydrazone ligand. because of the nonaxial ground state of dy-iii ion derived from a low-symmetrical crystal field, the title compound displays field-induced multiple relaxation processes which are of molecular and a dipolardipolar coupling origin, as revealed by combined experimental and theoretical investigations. the results demonstrate that such a mononuclear dysprosium(iii) compound with a low-symmetrical environment of magnetic center appears to be a model system for further investigations to shed light on the complex relaxation mechanism of lanthanide-based single ion magnets. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000345723300052 |
源URL | [http://ir.ciac.jl.cn/handle/322003/56213] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xue,Shufang,Ungur,L,Guo,Yun-Nan,et al. Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment[J]. inorganic chemistry,2014,53(23):12658-12663. |
APA | Xue,Shufang,Ungur,L,Guo,Yun-Nan,Tang,Jinkui,&Chibotaru,Liviu F..(2014).Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment.inorganic chemistry,53(23),12658-12663. |
MLA | Xue,Shufang,et al."Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment".inorganic chemistry 53.23(2014):12658-12663. |
入库方式: OAI收割
来源:长春应用化学研究所
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